caa a22 4500 60618080X CHVBK 20210128100808.0 cr unu---uuuuu 210128e20150101xx s 000 0 eng 10.1007/s10876-014-0739-8 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0739-8 Synthesis of Im3[Mo3(μ3-S)(μ-S2)3Br6]Br (Im=1-ethyl-3-methylimidazolium) in Ionic Liquid: A New Way of Breaking Up Chalcogenide Cluster Coordination Polymers [Elektronische Daten] [M. Sokolov, A. Rogachev, A. Virovets, D. Piryazev, V. Fedin] Reaction of 1D cluster coordination polymer Mo3S7Br4 with an ionic liquid composed of 1-ethyl-3-methylimidazolium bromide (ImBr) and AlBr3 in 2:1 molar ratio affords Im3[Mo3(μ3-S)(μ-S2)3Br6]Br (1) in high yield. X-ray structure of 1·CH 3 CN is reported. Graphical Abstract: Springer Science+Business Media New York, 2014 Molybdenum nationallicence Chalcogenide clusters nationallicence Coordination polymers nationallicence Ionic liquid nationallicence X-ray structure nationallicence Sokolov M. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut Rogachev A. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut Virovets A. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut Piryazev D. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut Fedin V. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 33-40 1040-7278 26:1<33 2015 26 10876 https://doi.org/10.1007/s10876-014-0739-8 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 brief-communication jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0739-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sokolov M. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Rogachev A. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Virovets A. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Piryazev D. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Fedin V. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, pr. Lavrentyeva 3, 630090, Novosibirsk, Russia aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 33-40 1040-7278 26:1<33 2015 26 10876