caa a22 4500 606180885 CHVBK 20210128100808.0 cr unu---uuuuu 210128e20150101xx s 000 0 eng 10.1007/s10876-014-0742-0 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0742-0 Thermal Detection, Synthesis, and Structural Characterization of Compounds in the Co-W-Cl System [Elektronische Daten] [Agnieszka Mos, Markus Ströbele, Hans-Jürgen Meyer] A thermal scanning method is performed for the detection of phases appearing in the Co-W-Cl system. This new procedure is based on the detection of thermal effects corresponding to the successive reduction stages when a reactive metal halide (WCl6) is heated with a metal (Co) powder under a constant heating rate (2°C/min). The conditions adapted there from are used for the synthesis of individual compounds. No less than five phases were identified by X-ray powder diffraction as W(Cox)Cl6, CoW2Cl10, "Co2W2Cl10”, (Co,W)Cl2, and CoW6Cl14. Springer Science+Business Media New York, 2014 Tungsten chloride cluster nationallicence Cobalt nationallicence DSC nationallicence Mos Agnieszka Section of Solid State and Theoretical Inorganic Chemistry, Department of Inorganic Chemistry, Eberhard Karls University Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany aut Ströbele Markus Section of Solid State and Theoretical Inorganic Chemistry, Department of Inorganic Chemistry, Eberhard Karls University Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany aut Meyer Hans-Jürgen Section of Solid State and Theoretical Inorganic Chemistry, Department of Inorganic Chemistry, Eberhard Karls University Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 187-198 1040-7278 26:1<187 2015 26 10876 https://doi.org/10.1007/s10876-014-0742-0 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0742-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Mos Agnieszka Section of Solid State and Theoretical Inorganic Chemistry, Department of Inorganic Chemistry, Eberhard Karls University Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany aut NATIONALLICENCE 700 1- Ströbele Markus Section of Solid State and Theoretical Inorganic Chemistry, Department of Inorganic Chemistry, Eberhard Karls University Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany aut NATIONALLICENCE 700 1- Meyer Hans-Jürgen Section of Solid State and Theoretical Inorganic Chemistry, Department of Inorganic Chemistry, Eberhard Karls University Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 187-198 1040-7278 26:1<187 2015 26 10876