caa a22 4500 606180907 CHVBK 20210128100808.0 cr unu---uuuuu 210128e20150101xx s 000 0 eng 10.1007/s10876-014-0748-7 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0748-7 Synthesis and Characterization of Oxygen/Sulfur-Bridged Incomplete Cubane-Type Clusters, [Mo3O n S4− n (Tm)3]+ ( n =0-3) [Elektronische Daten] [Haruo Akashi, Ryouichi Yoshida, Kazuhiro Moriwaki, Hideaki Takagi, Takashi Shibahara] The reactions of [Mo3S4(H2O)9]4+, [Mo3OS3(H2O)9]4+, [Mo3O2S2(H2O)9]4+, and [Mo3O3S(H2O)9]4+ with Na((C3H5N2S)3BH) (=NaTm, hydrotris(methimazolyl)borate) ligands produced [Mo3S4(Tm)3]Cl·2CH3OH·5H2O ([1]Cl·2CH3OH·5H2O), [Mo3OS3(Tm)3]Cl·CH3OH·6H2O ([2]Cl·CH3OH·6H2O), [Mo3O2S2(Tm)3]Cl·CH3OH·9H2O ([3]Cl·CH3OH·9H2O), and [Mo3O3S(Tm)3]Cl·CH3OH·6H2O ([4]Cl·CH3OH·6H2O), respectively. Hexafluorophosphate salts of the compounds [1]PF6·4CH3OH, [2]PF6·2CH3OH·4H2O, [3]PF6·CH3OH·2H2O, and [4]PF6·4CH3OH·3H2O have also been reported. Each molybdenum atom is bonded to the Tm ligand. All of the compounds (except cluster 3 and a chloride salt of cluster 4) have been structually characterized by X-ray structural analysis. The cyclic voltammograms of [1]PF6, [2]PF6, and [3]PF6 show one irreversible one-electron oxidation process (E pc (V): [1]PF6, 0.77; [2]PF6, 0.73; [3]PF6, 0.74, vs. SHE) and one reversible one-electron reduction process (E 1/2 (V): [1]PF6, −0.89; [2]PF6, −0.85; [3]PF6, −1.01, vs. SHE). The cyclic voltammogram of [4]PF6 shows one reversible one-electron oxidation process and one reversible one-electron reduction process (E 1/2 (V): [4]PF6, 0.76, −1.17, vs. SHE). Springer Science+Business Media New York, 2014 Molybdenum nationallicence Sulfur nationallicence Methimazolyl nationallicence Structure nationallicence Electrochemistry nationallicence Akashi Haruo Research Institute for Natural Sciences, Okayama University of Science, Ridai-cho, Kita-ku, 700-0005, Okayama, Japan aut Yoshida Ryouichi Research Institute for Natural Sciences, Okayama University of Science, Ridai-cho, Kita-ku, 700-0005, Okayama, Japan aut Moriwaki Kazuhiro Research Institute for Natural Sciences, Okayama University of Science, Ridai-cho, Kita-ku, 700-0005, Okayama, Japan aut Takagi Hideaki International Conservation Studies for Cultural Properties, Kibi International University, Igamachi 8, 716-8508, Takahashi-shi, Okayama, Japan aut Shibahara Takashi Department of Chemistry, Okayama University of Science, Ridai-cho, Kita-ku, 700-0005, Okayama, Japan aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 119-136 1040-7278 26:1<119 2015 26 10876 https://doi.org/10.1007/s10876-014-0748-7 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0748-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Akashi Haruo Research Institute for Natural Sciences, Okayama University of Science, Ridai-cho, Kita-ku, 700-0005, Okayama, Japan aut NATIONALLICENCE 700 1- Yoshida Ryouichi Research Institute for Natural Sciences, Okayama University of Science, Ridai-cho, Kita-ku, 700-0005, Okayama, Japan aut NATIONALLICENCE 700 1- Moriwaki Kazuhiro Research Institute for Natural Sciences, Okayama University of Science, Ridai-cho, Kita-ku, 700-0005, Okayama, Japan aut NATIONALLICENCE 700 1- Takagi Hideaki International Conservation Studies for Cultural Properties, Kibi International University, Igamachi 8, 716-8508, Takahashi-shi, Okayama, Japan aut NATIONALLICENCE 700 1- Shibahara Takashi Department of Chemistry, Okayama University of Science, Ridai-cho, Kita-ku, 700-0005, Okayama, Japan aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 119-136 1040-7278 26:1<119 2015 26 10876