caa a22 4500 60618094X CHVBK 20210128100808.0 cr unu---uuuuu 210128e20150101xx s 000 0 eng 10.1007/s10876-014-0761-x doi (NATIONALLICENCE)springer-10.1007/s10876-014-0761-x Syntheses, Structures, and Luminescence Properties of New Octahedral Cluster Complexes with Terminal Phenolate Ligands: [K(H2O)(CH3OH)3]2[Ph4P]2[ M 6Cl12(O-C6H4-F)6] ( M =Nb, Ta; Ph=phenyl) [Elektronische Daten] [Tao Xie, Aleksej Friedrich, Stefan Lochbrunner, Martin Köckerling] The cluster compounds [K(H2O)(CH3OH)3]2[Ph4P]2[M 6Cl12(para-O-C6H4-F)6] (M=Nb (1), Ta (2); Ph=phenyl) were obtained by the reaction of [Nb6Cl14(CH3OH)4]·6 CH3OH with potassium p-fluorophenolat and tetraphenylphosphonium chloride. 1 and 2 were crystallized from CH3OH and characterized by X-ray single-crystal diffraction, IR-,1H NMR-,UV-Vis- and luminescence spectroscopy. Springer Science+Business Media New York, 2014 Niobium nationallicence Cluster nationallicence Phenolate ligand nationallicence X-ray diffraction nationallicence Luminescense nationallicence Xie Tao Solid State Inorganic Chemistry Group, Institute of Chemistry, University of Rostock, Albert Einstein Straße 3a, 18059, Rostock, Germany aut Friedrich Aleksej Institute of Physics, University of Rostock, Universitätsplatz 3, 18051, Rostock, Germany aut Lochbrunner Stefan Institute of Physics, University of Rostock, Universitätsplatz 3, 18051, Rostock, Germany aut Köckerling Martin Solid State Inorganic Chemistry Group, Institute of Chemistry, University of Rostock, Albert Einstein Straße 3a, 18059, Rostock, Germany aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 223-232 1040-7278 26:1<223 2015 26 10876 https://doi.org/10.1007/s10876-014-0761-x text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0761-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Xie Tao Solid State Inorganic Chemistry Group, Institute of Chemistry, University of Rostock, Albert Einstein Straße 3a, 18059, Rostock, Germany aut NATIONALLICENCE 700 1- Friedrich Aleksej Institute of Physics, University of Rostock, Universitätsplatz 3, 18051, Rostock, Germany aut NATIONALLICENCE 700 1- Lochbrunner Stefan Institute of Physics, University of Rostock, Universitätsplatz 3, 18051, Rostock, Germany aut NATIONALLICENCE 700 1- Köckerling Martin Solid State Inorganic Chemistry Group, Institute of Chemistry, University of Rostock, Albert Einstein Straße 3a, 18059, Rostock, Germany aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 223-232 1040-7278 26:1<223 2015 26 10876