caa a22 4500 606180974 CHVBK 20210128100808.0 cr unu---uuuuu 210128e20150101xx s 000 0 eng 10.1007/s10876-014-0734-0 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0734-0 Advances in the Engineering of Near Infrared Emitting Liquid Crystals and Copolymers, Extended Porous Frameworks, Theranostic Tools and Molecular Junctions Using Tailored Re6 Cluster Building Blocks [Elektronische Daten] [Stéphane Cordier, Yann Molard, Konstantin Brylev, Yuri Mironov, Fabien Grasset, Bruno Fabre, Nikolay Naumov] At the occasion of the fiftieth birthday of the introduction of the term ‘metal atom cluster' by F. A. Cotton in inorganic chemistry, it is the good time to make a review on the advances in the engineering of molecular assemblies and nanomaterials based on octahedral Re6 metal atom clusters. The latter exhibit unique intrinsic structural and physicochemical properties (orthogonal disposition of metallic sites that can be selectively functionalized, photoluminescence, redox, generation of singlet oxygen) that make them relevant building blocks for the structuration at the nanometric scale and functionalization of hybrid organic-inorganic materials and supramolecular frameworks. After synthesis by solid state chemistry techniques at high temperature, inorganic precursors built up on face-capped $$\left[ {\left( {{\text{Re}}_{ 6} {\text{Y}}_{ 8}^{\text{i}} } \right){\text{Y}}_{ 6}^{\text{a}} } \right]$$ Re 6 Y 8 i Y 6 a cluster units (Y=chalcogen and/or halogen) can be functionalized via solution chemistry techniques or organic melts to form $$\left[ {\left( {{\text{Re}}_{ 6} {\text{Y}}_{ 8}^{\text{i}} } \right){\text{L}}_{ 6}^{\text{a}} } \right]$$ Re 6 Y 8 i L 6 a (L=CN, OH, various organic ligands ). This work reports advances in the synthesis of $$\left[ {\left( {{\text{Re}}_{ 6} {\text{Y}}_{ 8}^{\text{i}} } \right){\text{Y}}_{ 6}^{\text{a}} } \right]$$ Re 6 Y 8 i Y 6 a and $$\left[ {\left( {{\text{Re}}_{ 6} {\text{Y}}_{ 8}^{\text{i}} } \right){\text{L}}_{ 6}^{\text{a}} } \right]$$ Re 6 Y 8 i L 6 a cluster units as well as on their use in the elaboration of supramolecular frameworks, nanoparticles, hybrid nanomaterials (co-polymers and liquid crystals) and active molecular junctions. Springer Science+Business Media New York, 2014 Rhenium metal atom clusters nationallicence Nanoparticles nationallicence Supramolecular frameworks nationallicence Copolymers and Liquid crystals nationallicence Functional surfaces nationallicence Cordier Stéphane Institut des Sciences Chimiques de Rennes, UMR 6226 UR1-CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France aut Molard Yann Institut des Sciences Chimiques de Rennes, UMR 6226 UR1-CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France aut Brylev Konstantin Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev pr., 630090, Novosibirsk, Russia aut Mironov Yuri Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev pr., 630090, Novosibirsk, Russia aut Grasset Fabien Institut des Sciences Chimiques de Rennes, UMR 6226 UR1-CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France aut Fabre Bruno Institut des Sciences Chimiques de Rennes, UMR 6226 UR1-CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France aut Naumov Nikolay Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev pr., 630090, Novosibirsk, Russia aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 53-81 1040-7278 26:1<53 2015 26 10876 https://doi.org/10.1007/s10876-014-0734-0 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 review-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0734-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Cordier Stéphane Institut des Sciences Chimiques de Rennes, UMR 6226 UR1-CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France aut NATIONALLICENCE 700 1- Molard Yann Institut des Sciences Chimiques de Rennes, UMR 6226 UR1-CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France aut NATIONALLICENCE 700 1- Brylev Konstantin Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev pr., 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Mironov Yuri Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev pr., 630090, Novosibirsk, Russia aut NATIONALLICENCE 700 1- Grasset Fabien Institut des Sciences Chimiques de Rennes, UMR 6226 UR1-CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France aut NATIONALLICENCE 700 1- Fabre Bruno Institut des Sciences Chimiques de Rennes, UMR 6226 UR1-CNRS, Université de Rennes 1, Campus de Beaulieu, 35042, Rennes Cedex, France aut NATIONALLICENCE 700 1- Naumov Nikolay Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev pr., 630090, Novosibirsk, Russia aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 53-81 1040-7278 26:1<53 2015 26 10876