caa a22 4500 606181008 CHVBK 20210128100809.0 cr unu---uuuuu 210128e20150101xx s 000 0 eng 10.1007/s10876-014-0769-2 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0769-2 [Re6(μ3-Se)8]2+ Core-Containing Cluster Complexes with Isonicotinic Acid: Synthesis, Structural Characterization, and Hydrogen-Bonded Assemblies [Elektronische Daten] [William Corbin, Gary Nichol, Zhiping Zheng] Three new complexes of the [Re6(μ3-Se)8]2+ core-containing cluster with isonicotinic acid (INA) were synthesized and characterized by multinuclear NMR (1H and 31P) and high-resolution mass spectrometry. Their molecular and crystal structures were determined by single-crystal X-ray diffraction studies. Unusual degrees of deprotonation of the INA ligand(s) are observed in the crystal structure, possibly due to the activation by the Lewis acidic cluster core. Extensive hydrogen bonding interactions occurring between carboxylate groups of neighboring cluster units as revealed by crystallographic studies lead to the assembly of both linear and zigzag multi-cluster chains in the solid state. Springer Science+Business Media New York, 2014 Rhenium chalcogenide clusters nationallicence Deprotonation nationallicence Coordination nationallicence Crystal structure nationallicence Hydrogen Bond nationallicence Corbin William Department of Chemistry and Biochemistry, The University of Arizona, 85721, Tucson, AZ, USA aut Nichol Gary School of Chemistry, The University of Edinburgh, West Mains Road, EH9 3JJ, Edinburgh, Scotland, UK aut Zheng Zhiping Department of Chemistry and Biochemistry, The University of Arizona, 85721, Tucson, AZ, USA aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 279-290 1040-7278 26:1<279 2015 26 10876 https://doi.org/10.1007/s10876-014-0769-2 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0769-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Corbin William Department of Chemistry and Biochemistry, The University of Arizona, 85721, Tucson, AZ, USA aut NATIONALLICENCE 700 1- Nichol Gary School of Chemistry, The University of Edinburgh, West Mains Road, EH9 3JJ, Edinburgh, Scotland, UK aut NATIONALLICENCE 700 1- Zheng Zhiping Department of Chemistry and Biochemistry, The University of Arizona, 85721, Tucson, AZ, USA aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/1(2015-01-01), 279-290 1040-7278 26:1<279 2015 26 10876