caa a22 4500 606181075 CHVBK 20210128100809.0 cr unu---uuuuu 210128e20151101xx s 000 0 eng 10.1007/s10876-015-0888-4 doi (NATIONALLICENCE)springer-10.1007/s10876-015-0888-4 Crystal Structure and Catalytic Elimination of Methanol from Two Novel Organic-Inorganic Hybrid Based on Silicomolybdenate, Silicotungstate and 2-Aminopyrimidine [Elektronische Daten] [Xiao-Miao Chen, Yi-Lan Huang, Qing Cai, Yu-Zhe Han, Qian Deng] Two new organic-inorganic hybrid, namely, (C4H7N3)2·(SiMo12O40)·(C4H5N3)2·(H2O)2 (1), (C4H7N3)2·(SiW12O40)·(C4H5N3)2·(H2O)2 (2) were synthesized by reaction of silicomolybdenate/silicotungstate and 2-aminopyrimidine and characterized by FT-IR, UV-vis, Fluorescence and single-crystal X-ray diffraction techniques. Compound 1 exhibit a two-dimensional supramolecular network via hydrogen bond interactions. Compound 2 show a three-dimensional supramolecular extended by two-dimensional pore structure constructed by the 2-aminopyrimidine molecules. Compound 1 emits green fluorescence and compounds 2 emits cyan fluorescence. The catalytic experimental results showed that compound 2 is active for catalytic oxidation of methanol in a continuous-flow fixed-bed micro-reactor, when the initial concentration of methanol is 5.37g·m−3 in air and flow rate is 5mL·min−1 at 90°C, corresponding to the elimination rate of methanol is 53.09% which is significant in environment protection. Springer Science+Business Media New York, 2015 Silicomolybdenate nationallicence Silicotungstate nationallicence 2-Aminopyrimidine nationallicence Catalytic elimination nationallicence Methanol nationallicence Chen Xiao-Miao Special and Key Laboratory of Functional Materials and Resource Chemistry of Guizhou Provincial Education Department, Anshun University, 561000, Anshun, China aut Huang Yi-Lan College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, 411201, Xiangtan, China aut Cai Qing Chemistry Department, City College of New York, City University of New York, 10016, New York, NY, USA aut Han Yu-Zhe College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, 411201, Xiangtan, China aut Deng Qian College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, 411201, Xiangtan, China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/6(2015-11-01), 1943-1957 1040-7278 26:6<1943 2015 26 10876 https://doi.org/10.1007/s10876-015-0888-4 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0888-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Chen Xiao-Miao Special and Key Laboratory of Functional Materials and Resource Chemistry of Guizhou Provincial Education Department, Anshun University, 561000, Anshun, China aut NATIONALLICENCE 700 1- Huang Yi-Lan College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, 411201, Xiangtan, China aut NATIONALLICENCE 700 1- Cai Qing Chemistry Department, City College of New York, City University of New York, 10016, New York, NY, USA aut NATIONALLICENCE 700 1- Han Yu-Zhe College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, 411201, Xiangtan, China aut NATIONALLICENCE 700 1- Deng Qian College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, 411201, Xiangtan, China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/6(2015-11-01), 1943-1957 1040-7278 26:6<1943 2015 26 10876