caa a22 4500 60618113X CHVBK 20210128100809.0 cr unu---uuuuu 210128e20151101xx s 000 0 eng 10.1007/s10876-015-0921-7 doi (NATIONALLICENCE)springer-10.1007/s10876-015-0921-7 Jelliumatic Shell Model [Elektronische Daten] [Boon Teo, Shi-Yao Yang] Jelliumatic shell model (JSM), a variant of jellium model (JM), is proposed in an attempt to rationalize the electron counts of four metal clusters that "violate” the global jelliumatic model (GJM): (1) for the spherically shaped [Cu28H15(S2CNR)12]+, the global jelliumatic electron (gje) count of 30 is partitioned into three electronic shells of {[H]−@[Cu4H6]2+@[Cu24H8(S2CNR)12]}+ with 2, 8, and 20 jelliumatic shell electrons (jse); each shell conforms to JM for a spherical shape; (2) for the [Cu20H11{S2P(O i Pr)2}9] cluster, the gje of 22 can be divided into two electronic shells of {[Cu2H5]3−@[Cu18H6L9]3+} with jse of 10 and 12, respectively; each shell satisfies JM for a prolate ellipsoidal shape; (3) for the [Cu32H20{S2P(O i Pr)2}12] cluster, with an overall prolate molecular shape, the gje of 40 can be subdivided into three electronic shells of {[Cu12H6]2+@[Cu2H6]4−@[Cu18H8L12]2+} with 16, 12, and 12 jse, in harmony with an oblate ellipsoidal shape for the [Cu12H6]2+ core and prolate ellipsoidal shapes for the [Cu2H6]4− and [Cu18H8L12]2+ shells, respectively; and (4) for the spherical-shaped intermetalloid {[Sn]4−@[Cu12]4+@[Sn20]12−}12− and {[As]3−@[Ni12]8−@[As20]8+}3− clusters, the gje of 108 can be apportioned into three electronic shells (charges as shown) with 8, 8, and 92 jse with each shell being in compliance with JM for a spherical shape. Springer Science+Business Media New York, 2015 Jelliumatic shell model nationallicence Global jelliumatic model nationallicence Magic numbers nationallicence Copper hydride clusters nationallicence Intermetalloid clusters nationallicence Teo Boon College of Chemistry and Chemical Engineering, Xiamen University, 361005, Xiamen, Fujian, China aut Yang Shi-Yao College of Chemistry and Chemical Engineering, Xiamen University, 361005, Xiamen, Fujian, China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/6(2015-11-01), 1923-1941 1040-7278 26:6<1923 2015 26 10876 https://doi.org/10.1007/s10876-015-0921-7 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0921-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Teo Boon College of Chemistry and Chemical Engineering, Xiamen University, 361005, Xiamen, Fujian, China aut NATIONALLICENCE 700 1- Yang Shi-Yao College of Chemistry and Chemical Engineering, Xiamen University, 361005, Xiamen, Fujian, China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/6(2015-11-01), 1923-1941 1040-7278 26:6<1923 2015 26 10876