caa a22 4500 606181148 CHVBK 20210128100809.0 cr unu---uuuuu 210128e20151101xx s 000 0 eng 10.1007/s10876-015-0889-3 doi (NATIONALLICENCE)springer-10.1007/s10876-015-0889-3 Synthesis, Structure and Property of a 3D Heterometallic Complex Constructed by Trinuclear [In2Co(OH)2(COO)4] Cluster and BTC Ligand [Elektronische Daten] [Sa-Ying Li, Zhi-Hong Liu] A novel indium-cobalt heterometallic complex, [C6H11N2]2[In2Co(OH)2 (BTC)2Br2], has been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, XRD, TG-DTA, and single crystal X-ray diffraction. It crystallizes in the monoclinic system with space group P21/c. Its structure is characterized as a 3D open framework constructed by [In2Co(OH)2(COO)4] cluster subunit and the 1,3,5-benzenetricarboxylate ligand. The used IL cations [C6H11N2]+ are located in the channels and compensate for the negative charges of framework. Furthermore, its fluorescent property and ion exchange property have also been studied. Springer Science+Business Media New York, 2015 Heteronuclear cluster nationallicence Ionothermal synthesis nationallicence Crystal structure nationallicence Fluorescent property nationallicence Ion exchange property nationallicence Li Sa-Ying Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut Liu Zhi-Hong Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/6(2015-11-01), 1959-1970 1040-7278 26:6<1959 2015 26 10876 https://doi.org/10.1007/s10876-015-0889-3 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0889-3 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Li Sa-Ying Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut NATIONALLICENCE 700 1- Liu Zhi-Hong Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/6(2015-11-01), 1959-1970 1040-7278 26:6<1959 2015 26 10876