caa a22 4500 606181199 CHVBK 20210128100809.0 cr unu---uuuuu 210128e20150501xx s 000 0 eng 10.1007/s10876-014-0771-8 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0771-8 Synthesis and Characterization of a New Noncentrosymmetric Dihydrogenmonophosphate [C12H13N2O]H2PO4 [Elektronische Daten] [Sami Soukrata, Mohamed Belhouchet, Tahar Mhiri] The organic-inorganic hybrid material [C12H13N2O]H2PO4 has been synthesized at room temperature by slow evaporation. The compound crystallizes in the noncentrosymmetric orthorhombic space group P212121 with the lattice parameters a=4.75 (5) Å, b=10.26 (5) Å, c=27.09 (3) Å, Z=4 and V=1323.3 (2) Å3. The crystal structure has been determined and refined to R1=0.047 and wR2=0.120 using 2870 independent reflections. The atomic arrangement can be described by infinite anionic chains running parallel to the a axis. The organic cations are linked to the inorganic chains by hydrogen bonds so as to build a two-dimensional network. The infrared spectroscopy confirms the presence of the organic group and the anionic entities. Concerning the differential scanning calorimetry, it revealed one phase transition at 71°C. Thermal analysis was performed to study its thermal stability. Besides, the impedance spectroscopy study, reported in the sample, reveals that the conduction in the material is due to a Grotthus mechanism. Springer Science+Business Media New York, 2014 Inorganic compounds nationallicence Chemical synthesis nationallicence Infrared and NMR spectroscopy nationallicence Thermal analysis nationallicence Electrical conductivity nationallicence Soukrata Sami Laboratoire Physico-Chimie de l'Etat Solide. Département de Chimie. Faculté des Sciences de Sfax, Université de Sfax, 3018, Sfax, Tunisie aut Belhouchet Mohamed Laboratoire Physico-Chimie de l'Etat Solide. Département de Chimie. Faculté des Sciences de Sfax, Université de Sfax, 3018, Sfax, Tunisie aut Mhiri Tahar Laboratoire Physico-Chimie de l'Etat Solide. Département de Chimie. Faculté des Sciences de Sfax, Université de Sfax, 3018, Sfax, Tunisie aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 835-849 1040-7278 26:3<835 2015 26 10876 https://doi.org/10.1007/s10876-014-0771-8 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0771-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Soukrata Sami Laboratoire Physico-Chimie de l'Etat Solide. Département de Chimie. Faculté des Sciences de Sfax, Université de Sfax, 3018, Sfax, Tunisie aut NATIONALLICENCE 700 1- Belhouchet Mohamed Laboratoire Physico-Chimie de l'Etat Solide. Département de Chimie. Faculté des Sciences de Sfax, Université de Sfax, 3018, Sfax, Tunisie aut NATIONALLICENCE 700 1- Mhiri Tahar Laboratoire Physico-Chimie de l'Etat Solide. Département de Chimie. Faculté des Sciences de Sfax, Université de Sfax, 3018, Sfax, Tunisie aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 835-849 1040-7278 26:3<835 2015 26 10876