caa a22 4500 606181202 CHVBK 20210128100810.0 cr unu---uuuuu 210128e20150501xx s 000 0 eng 10.1007/s10876-014-0770-9 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0770-9 Synthesis, Structure, Luminescence and Gas Sorption of a 3D Zn(II) Polymer Material with Rutile Topology [Elektronische Daten] [Jun Wang, Xi-Ren Wu, Jian-Qiang Liu, Lu Lu, Qing-Lin Li, Jia-Min Wu, Yi Hu, Mei-Shan Li, Jian-Hui Man] Solvothermal reaction of 1,3,5-benzenetricarboxylic acid (H3btc) with zinc acetate yielded a compound with chemical formulae (Me2NH2)[Zn(btc)]·H2O·DMA (1) (btc=1,3,5-benzenetricarboxylate, DMA=N,N-dimethylacetamide). 1 shows a 3D non-interpenetrating rutile topological net, which has 1D channels located Me2NH2 counter anion and guest DMA and H2O molecules. The material has no significant adsorption for CO2 and N2 gases upon desolvation by long-time thermal activation, indicating that access to the void space is blocked by the large and immovable anions. The luminescence study indicates that the title compound emits bright red fluorescence compared to the free ligand at room temperature. Springer Science+Business Media New York, 2014 Luminescence nationallicence Gas sorption nationallicence Cluster nationallicence Wang Jun Institute of Functionalized Materials, Sichuan University of Science & Engineering, 643000, Zigong, People's Republic of China aut Wu Xi-Ren School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut Liu Jian-Qiang School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut Lu Lu Institute of Functionalized Materials, Sichuan University of Science & Engineering, 643000, Zigong, People's Republic of China aut Li Qing-Lin School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut Wu Jia-Min School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut Hu Yi School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut Li Mei-Shan School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut Man Jian-Hui School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 827-834 1040-7278 26:3<827 2015 26 10876 https://doi.org/10.1007/s10876-014-0770-9 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0770-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Jun Institute of Functionalized Materials, Sichuan University of Science & Engineering, 643000, Zigong, People's Republic of China aut NATIONALLICENCE 700 1- Wu Xi-Ren School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut NATIONALLICENCE 700 1- Liu Jian-Qiang School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut NATIONALLICENCE 700 1- Lu Lu Institute of Functionalized Materials, Sichuan University of Science & Engineering, 643000, Zigong, People's Republic of China aut NATIONALLICENCE 700 1- Li Qing-Lin School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut NATIONALLICENCE 700 1- Wu Jia-Min School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut NATIONALLICENCE 700 1- Hu Yi School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut NATIONALLICENCE 700 1- Li Mei-Shan School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut NATIONALLICENCE 700 1- Man Jian-Hui School of Pharmacy, Guangdong Medical College, 523808, Dongguan, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 827-834 1040-7278 26:3<827 2015 26 10876