caa a22 4500 60618127X CHVBK 20210128100810.0 cr unu---uuuuu 210128e20150501xx s 000 0 eng 10.1007/s10876-015-0879-5 doi (NATIONALLICENCE)springer-10.1007/s10876-015-0879-5 Heterometallic Inorganic-Organic Hybrids Containing Polynuclear Halobismuthates Anions and d-Metal Coordination Cations: Structure and Physical Properties [Elektronische Daten] [Chun-Cai Lin, Peng Wang, Lu Jin, Hao-Hong Li, Shu-Kun Lin, Zhi-Rong Chen] Two new heterometallic inorganic-organic hybrids containing polynuclear halobismuthates anions and ruthenium complex cations, i.e., [Ru(tpy)2]2[(Bi2I7Cl2)·I] (1), [Ru(bipy)2(bipyo]2(Bi4I16) (2), (tpy=2,2′:6′,2″-terpyridine, bipy=2,2′-bipyridine, bipyo=2,2′-bipyridine-6-olato) have been structurally determined. These hybrids are the rare examples of mixed-metal halobismuthates containing photochemically active coordination cations, and 1 consists of mixed halo atoms. C-H···I hydrogen bonds among halobismuthates clusters and [Ru(tpy)2]2+/[Ru(bipy)2(bipyo]2+ countercations contribute to the formation of a 3-D network. Moreover, their absorption spectra and photoluminescence have also been discussed, and their absorption edges fall in the range of those of semiconductors. Graphical Abstract: Two new heterometallic inorganic-organic hybrids containing polynuclear halobismuthates anions and ruthenium complex cations have been structurally determined, which represent the rare examples of mixed-metal halobismuthates containing photochemically active coordination cation and mixed halo atoms. C-H···I hydrogen bonds contribute to the formation of a 3-D network, and their absorption spectra and photoluminescence have also been discussed. Springer Science+Business Media New York, 2015 Organic-inorganic hybrid nationallicence Iodobismuthate nationallicence Photoluminescence nationallicence Lin Chun-Cai College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut Wang Peng College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut Jin Lu College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut Li Hao-Hong College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut Lin Shu-Kun College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut Chen Zhi-Rong College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 1011-1022 1040-7278 26:3<1011 2015 26 10876 https://doi.org/10.1007/s10876-015-0879-5 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0879-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Lin Chun-Cai College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Wang Peng College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Jin Lu College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Li Hao-Hong College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Lin Shu-Kun College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut NATIONALLICENCE 700 1- Chen Zhi-Rong College of Chemistry, Fuzhou University, 350116, Fuzhou, Fujian, China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 1011-1022 1040-7278 26:3<1011 2015 26 10876