caa a22 4500 606181288 CHVBK 20210128100810.0 cr unu---uuuuu 210128e20150501xx s 000 0 eng 10.1007/s10876-014-0782-5 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0782-5 Hydrothermal Processing, Structural Characterization and Theoretical Calculations of Two Copper (I) Complexes with 1,10-phenanthroline Derivatives Ligand: 2-(4-Methoxyphenyl)-1 H -imidazo [4, 5-f] [1,10] phenanthroline [Elektronische Daten] [Yan-Ju Huang, Yong-Sheng Yan, Ya-Ru Pan, Hong-Yan Zhang] In this paper, we report the obtention of two copper (I) metal-organic complexes [Cu(LH)2Cl] 1 and [Cu2L2]n 2 (LH=2-(4-Methoxyphenyl)-1H-imidazo[4,5-f][1,10] phenanthroline) by hydrothermal processing and structural characterization by elemental analysis, thermogravimetric analysis, single-crystal X-ray diffraction and theoretical calculations in Gaussian 09. The pH value of the reaction plays a key role in controlling the structures of the metal-organic complexes. Based on the structures of 1 and 2, we found that the pH influence on the structure of the complexes is, in fact, high pH value will favor the complex 2 produced. Springer Science+Business Media New York, 2014 Crystal structure nationallicence Hydrothermal processing nationallicence pH value nationallicence Huang Yan-Ju Department of Chemistry, Tonghua Normal University, 134002, Tonghua, People's Republic of China aut Yan Yong-Sheng School of Chemistry and Chemical Engineering, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut Pan Ya-Ru Department of Chemistry, Tonghua Normal University, 134002, Tonghua, People's Republic of China aut Zhang Hong-Yan Department of Chemistry, Tonghua Normal University, 134002, Tonghua, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 925-936 1040-7278 26:3<925 2015 26 10876 https://doi.org/10.1007/s10876-014-0782-5 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0782-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Huang Yan-Ju Department of Chemistry, Tonghua Normal University, 134002, Tonghua, People's Republic of China aut NATIONALLICENCE 700 1- Yan Yong-Sheng School of Chemistry and Chemical Engineering, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut NATIONALLICENCE 700 1- Pan Ya-Ru Department of Chemistry, Tonghua Normal University, 134002, Tonghua, People's Republic of China aut NATIONALLICENCE 700 1- Zhang Hong-Yan Department of Chemistry, Tonghua Normal University, 134002, Tonghua, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 925-936 1040-7278 26:3<925 2015 26 10876