caa a22 4500 60618144X CHVBK 20210128100811.0 cr unu---uuuuu 210128e20150501xx s 000 0 eng 10.1007/s10876-014-0788-z doi (NATIONALLICENCE)springer-10.1007/s10876-014-0788-z Synthesis, Structures and Properties of Two New Coordination Polymers with Unprecedented Water Cluster [Elektronische Daten] [Shu Wang, Ling Zhang, Fen Jiang, Qin Huang] Two new complexes, [Eu2(NIPH)2(H2O)14](HNIPH)2(H2O)7 (1) [Co2(abtc)(phen)4(H2O)]·12(H2O) (2) (H2NIPH=5-nitroisophthalic acid, H4abtc=3,3′,5,5′-azobenzenetetracarboxylic acid, phen=1,10-phenanthroline, DMF=N,N′-dimethylformamide) have been synthesized and characterized by infrared spectrum, thermal gravimetric analysis, X-ray single crystal diffraction and photoluminescence properties. Complex 1 upon slow evaporation at room temperature gave a 0-D structure, and seven independent water molecules and their equivalent held together by hydrogen bonds with an ordered proton arrangement form a 1-D hydrogen-bonded water tape. An unusual water tape notated T10(0)A0 is observed in 2. A 1-D water tape by connecting five-ten-five membered water rings through hydrogen bonds. Multiple hydrogen bonds and π-π stacking interactions play important roles in the formation of the 3-D networks. Fascinatingly, these lattice water molecules display unprecedented water cluster and play important roles in the stabilizing the whole network. Springer Science+Business Media New York, 2014 5-Nitroisophthalic acid nationallicence 3,3′,5,5′-Azobenzenetetracarboxylic acid nationallicence Water cluster nationallicence Fluorescence nationallicence Wang Shu College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, 530006, Nanning, People's Republic of China aut Zhang Ling College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, 530006, Nanning, People's Republic of China aut Jiang Fen College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, 530006, Nanning, People's Republic of China aut Huang Qin College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, 530006, Nanning, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 959-972 1040-7278 26:3<959 2015 26 10876 https://doi.org/10.1007/s10876-014-0788-z text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0788-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Shu College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, 530006, Nanning, People's Republic of China aut NATIONALLICENCE 700 1- Zhang Ling College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, 530006, Nanning, People's Republic of China aut NATIONALLICENCE 700 1- Jiang Fen College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, 530006, Nanning, People's Republic of China aut NATIONALLICENCE 700 1- Huang Qin College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, 530006, Nanning, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 959-972 1040-7278 26:3<959 2015 26 10876