caa a22 4500 606181458 CHVBK 20210128100811.0 cr unu---uuuuu 210128e20150501xx s 000 0 eng 10.1007/s10876-014-0789-y doi (NATIONALLICENCE)springer-10.1007/s10876-014-0789-y Potassium-Crownether Host-Guest Cation Directing the Assembly of a Unique Eicosanuclear Supra-Cubic Cage-Like W/S/Cu Cluster [Elektronische Daten] [Jin-Fang Zhang, Wei-Tao Chen, Yin-Lin Wang, Chi Zhang] A unique eicosanuclear heterothiometallic W/S/Cu octameric cluster [K(dibenzo-18-crown-6)(DMF)(CH3CN)]4[W8S32Cu12] (1), induced by potassium-crownether host-guest cation, was synthesized by the reaction of (NH4)2WS4, CuI, KI, dibenzo-18-crown-6 in DMF. 1 was characterized by elemental analyses, IR, UV-Vis, thermogravimetric analyses (TGA), X-ray powder and single crystal diffractions. The cation of 1 has the host-guest configuration, where K+ is embeded in the center of dibenzo-18-crown-6. The anionic architecture of 1 exhibits a supra-cubic cage, constructed by four nest-shaped clusters [W(µ1-S)(µ3-S)3Cu3]+ and four flywheel-shaped clusters [W(µ2-S)3(µ4-S)Cu3]+ linking each other through shared Cu atoms. Springer Science+Business Media New York, 2014 Heterothiometallic W/S/Cu cluster nationallicence Eicosanuclear supra-cubic cage nationallicence Host-guest cation nationallicence Zhang Jin-Fang China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut Chen Wei-Tao China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut Wang Yin-Lin China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut Zhang Chi China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 973-982 1040-7278 26:3<973 2015 26 10876 https://doi.org/10.1007/s10876-014-0789-y text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0789-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhang Jin-Fang China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut NATIONALLICENCE 700 1- Chen Wei-Tao China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut NATIONALLICENCE 700 1- Wang Yin-Lin China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut NATIONALLICENCE 700 1- Zhang Chi China-Australia Joint Research Center for Functional Molecular Materials, Scientific Research Academy, Jiangsu University, 212013, Zhenjiang, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/3(2015-05-01), 973-982 1040-7278 26:3<973 2015 26 10876