caa a22 4500 606181490 CHVBK 20210128100811.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0797-y doi (NATIONALLICENCE)springer-10.1007/s10876-014-0797-y Hydrothermal Syntheses, Crystal Structure, and Photophysical Property of a Novel 2D Coordination Polymer with Holo-Directed Geometry of Lead(II) [Elektronische Daten] [Li Yan, Chao Zeng, Chuan-Bi Li] One coordination polymer [Pb(ctpt)2(aic)·3H2O]n (1) [ctpt=2-(4-Chloro-phenyl)-1H-1,3,7,8-tetraaza-cyclopenta[l]phenanthrene, aic=5-Amino-isophthalic carboxylate] has been synthesized by hydrothermal reaction system and characterized by elemental analysis, thermogravimetric (TG) analysis, infrared spectrum and single-crystal X-ray diffraction. Complex 1 crystallizes with an N-donor chelating ligand and an aromatic dicarboxylate linker. Single-crystal X-ray diffraction reveals that 1 exhibits one-dimensional (1D) chain structure, and N-H···O hydrogen bonds lead the 1D chain structure to 2D layer framework. TG analysis shows clear courses of weight loss, which corresponds to the decomposition of different ligands. The photoluminescence properties of the coordination polymer have also been investigated. Springer Science+Business Media New York, 2014 Lead nationallicence Holo-directed structure nationallicence Thermal stability nationallicence Fluorescence nationallicence Yan Li Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, 136000, Siping, People's Republic of China aut Zeng Chao Beijing Zhou Kou Dian Middle School, 102405, Beijing, People's Republic of China aut Li Chuan-Bi Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, 136000, Siping, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1067-1076 1040-7278 26:4<1067 2015 26 10876 https://doi.org/10.1007/s10876-014-0797-y text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0797-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yan Li Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, 136000, Siping, People's Republic of China aut NATIONALLICENCE 700 1- Zeng Chao Beijing Zhou Kou Dian Middle School, 102405, Beijing, People's Republic of China aut NATIONALLICENCE 700 1- Li Chuan-Bi Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, 136000, Siping, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1067-1076 1040-7278 26:4<1067 2015 26 10876