caa a22 4500 606181504 CHVBK 20210128100811.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0807-0 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0807-0 A New 1-D Organic-Inorganic Hybrid Dimer Chain Complex Constructed by Manganese(III)-(Schiff-base) and [WO4]2− Unit [Elektronische Daten] [Qiong Wu, Huankang Liu, Xiaoling Hu, Jing Lu, Hai Wang] The reaction between Metal-Schiff-base complexes and lacunary POM moieties leads to the isolation of a new organic-inorganic hybrid dimer chain complex, [Mn(salen)]2[WO4]·2CH3OH (1) (salen=N,N′-ethylene-bis(salicylideneiminate)), which have been characterized by elemental analyses, IR spectra, and single-crystal X-ray diffraction. Crystal data for 1: Triclinic, P-1, a=13.502(5)Å, b=16.342(5)Å, c=16.902(5)Å, α=90.323(5)°, β=107.835(5)°, γ=97.185(5)°. Structural analyses reveal that 1 represents the first example of out-of-plane manganese dimer chain complex linked by pure inorganic radical. Magnetic susceptibility study reveals that there was overall antiferromagnetic coupling in the complex. Springer Science+Business Media New York, 2014 Schiff-base nationallicence Chain nationallicence Manganese dimer nationallicence Inorganic linkage nationallicence Magnetic properties nationallicence Wu Qiong Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Liu Huankang Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Hu Xiaoling Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Lu Jing Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Wang Hai Key Laboratory of Yunnan Provincial Higher Education Institutions for Organic Optoelectronic Materials and Devices, Kunming University, 650214, Kunming, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1203-1213 1040-7278 26:4<1203 2015 26 10876 https://doi.org/10.1007/s10876-014-0807-0 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0807-0 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wu Qiong Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Liu Huankang Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Hu Xiaoling Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Lu Jing Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Wang Hai Key Laboratory of Yunnan Provincial Higher Education Institutions for Organic Optoelectronic Materials and Devices, Kunming University, 650214, Kunming, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1203-1213 1040-7278 26:4<1203 2015 26 10876