caa a22 4500 606181539 CHVBK 20210128100811.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0784-3 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0784-3 Bis(imidazole) Cation Templates and Subtle Effect: Syntheses and Characterization of Three New Pb(II) Halide Supramolecular Polymers [Elektronische Daten] [Chao-Hai Wang, Cheng-Jie Ma, Zhi-Peng Huang, Yu-Xia Zai, Qing Yang, Li Li, Yu Liang, Yun-Yin Niu] Three novel cation-templated complexes, {(dmb)[Pb2Cl2I4]}n (1), {(ddb)[Pb2I6]}n (2), {(dmh)[Pb2I6]}n (3) (dmb=α,α-di(3-methylimidozole-1-yl)benzene dichloride, ddb=α,α-di(2,3-dimethylimidozole-1-yl)benzene dichloride, dmh=1,6-di(3-methylimidozole) hexane have been synthesized via the self-assembly reaction in solution. The X-ray crystallography shows these compounds were all composed of imidazole organic dications and halocluster anions. It is the H-bonds and electrostatic interactions between the organic counteractions and inorganic moieties that do the contribution to the crystal packing. These compounds have been further characterized by IR spectroscopy, UV-Vis spectra and thermostability properties. Springer Science+Business Media New York, 2014 Cation templates nationallicence Methylimidazolium nationallicence Inorganic/organic interactions nationallicence Wang Chao-Hai College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut Ma Cheng-Jie College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut Huang Zhi-Peng College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut Zai Yu-Xia College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut Yang Qing College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut Li Li College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut Liang Yu College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut Niu Yun-Yin College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1027-1039 1040-7278 26:4<1027 2015 26 10876 https://doi.org/10.1007/s10876-014-0784-3 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0784-3 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Chao-Hai College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut NATIONALLICENCE 700 1- Ma Cheng-Jie College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut NATIONALLICENCE 700 1- Huang Zhi-Peng College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut NATIONALLICENCE 700 1- Zai Yu-Xia College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut NATIONALLICENCE 700 1- Yang Qing College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut NATIONALLICENCE 700 1- Li Li College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut NATIONALLICENCE 700 1- Liang Yu College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut NATIONALLICENCE 700 1- Niu Yun-Yin College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1027-1039 1040-7278 26:4<1027 2015 26 10876