caa a22 4500 606181563 CHVBK 20210128100811.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0822-1 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0822-1 A New Metal-Organic Framework Constructed from Trinuclear {Cd3} Clusters as Secondary Building Units [Elektronische Daten] [Hui-Yan Ma, Chang-Hua Su, Jie Yin, Yun-Wu Li, Xin Shao] A novel metal-organic framework, {[H2N(CH3)2][Cd3(BTC)2(BTA)(H2O)2]·2H2O}n (1) (H3BTC=1,3,5-benzenetricarboxylate, HBTA=1H-Benzotriazolate), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction analysis. Compound 1 represents a new (3,3,6)-connected structural topology constructed by trinuclear {Cd3} clusters as secondary building units. Moreover, the luminescence properties of 1 have been well investigated. Springer Science+Business Media New York, 2015 CdII-MOF nationallicence Trinuclear cluster SBUs nationallicence New topology nationallicence Luminescence properties nationallicence Ma Hui-Yan School of Materials Science and Engineering, Liaocheng University, 252000, Liaocheng, People's Republic of China aut Su Chang-Hua School of Materials Science and Engineering, Liaocheng University, 252000, Liaocheng, People's Republic of China aut Yin Jie School of Materials Science and Engineering, Liaocheng University, 252000, Liaocheng, People's Republic of China aut Li Yun-Wu School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, 252000, Liaocheng, People's Republic of China aut Shao Xin School of Materials Science and Engineering, Liaocheng University, 252000, Liaocheng, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1403-1411 1040-7278 26:4<1403 2015 26 10876 https://doi.org/10.1007/s10876-014-0822-1 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0822-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ma Hui-Yan School of Materials Science and Engineering, Liaocheng University, 252000, Liaocheng, People's Republic of China aut NATIONALLICENCE 700 1- Su Chang-Hua School of Materials Science and Engineering, Liaocheng University, 252000, Liaocheng, People's Republic of China aut NATIONALLICENCE 700 1- Yin Jie School of Materials Science and Engineering, Liaocheng University, 252000, Liaocheng, People's Republic of China aut NATIONALLICENCE 700 1- Li Yun-Wu School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, 252000, Liaocheng, People's Republic of China aut NATIONALLICENCE 700 1- Shao Xin School of Materials Science and Engineering, Liaocheng University, 252000, Liaocheng, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1403-1411 1040-7278 26:4<1403 2015 26 10876