caa a22 4500 606181598 CHVBK 20210128100811.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0821-2 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0821-2 Synthesis, Structures and Luminescent Properties of 3D Copper(I) 1,2,4-Triazolates Containing Cubic Cu4X4 Clusters (X=Cl, Br) [Elektronische Daten] [Ze-Jie Lv, Ping-Ning Jin, Yong-Hui Wang, Xiu-Bao Wei, Guang Yang] Reactions of 3,5-disubstituted-1,2,4-triazoles with CuX2 (X=Cl, Br) under hydrothermal condition yield six copper(I) triazolates: [Cu2(3,5- n Bu2tz)Cl]n (1), [Cu2(3,5- i Bu2tz)Cl]n (2), {Cu2(3,5-(C6H11)2tz)Cl}n (3), [Cu2(3,5- s Bu2tz)Br]n (4), {Cu2(3,5-(C6H11)2tz)Br}n (5), {Cu2[3,5-(p-Tol)2tz]Br}n (6), where 3,5- n Bu2tz, 3,5- i Bu2tz, 3,5- s Bu2tz are 3,5-dibutyl-1,2,4-triazolate, 3,5-dii-butyl-1,2,4-triazolate, 3,5-dis-butyl-1,2,4-triazolate; 3,5-(C6H11)2tz is 3,5-dicyclohexyl-1,2,4-triazolate; 3,5-(p-Tol)2tz is 3,5-di-p-tolyl-1,2,4-triazolate. X-ray analysis demonstrates that all of these complexes are isostructural and exhibit a 3D structure carrying cubic Cu4Cl4 or Cu4Br4 clusters. While 4 and 5 luminesce with maxima at 571 and 619nm, others are silent under UV irradiation at room temperature. Springer Science+Business Media New York, 2014 Copper(I) nationallicence Triazole nationallicence Structure nationallicence Cu4Cl4 cluster nationallicence Cu4Br4 cluster nationallicence Lv Ze-Jie College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, China aut Jin Ping-Ning Analysis & Test Laboratory, Department of Basic Medical Science, Xinxiang Medical University, 453000, Xinxiang, China aut Wang Yong-Hui The Centre of Supervision and Inspection of Quality and Technique at Sanmenxia, 472000, Sanmenxia, China aut Wei Xiu-Bao College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, China aut Yang Guang College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1389-1401 1040-7278 26:4<1389 2015 26 10876 https://doi.org/10.1007/s10876-014-0821-2 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0821-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Lv Ze-Jie College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, China aut NATIONALLICENCE 700 1- Jin Ping-Ning Analysis & Test Laboratory, Department of Basic Medical Science, Xinxiang Medical University, 453000, Xinxiang, China aut NATIONALLICENCE 700 1- Wang Yong-Hui The Centre of Supervision and Inspection of Quality and Technique at Sanmenxia, 472000, Sanmenxia, China aut NATIONALLICENCE 700 1- Wei Xiu-Bao College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, China aut NATIONALLICENCE 700 1- Yang Guang College of Chemistry and Molecular Engineering, Zhengzhou University, 450001, Zhengzhou, China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1389-1401 1040-7278 26:4<1389 2015 26 10876