caa a22 4500 606181628 CHVBK 20210128100811.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0796-z doi (NATIONALLICENCE)springer-10.1007/s10876-014-0796-z Synthesis, Crystal Structure and Magnetic Property of Double μ 6-CO3 2− Centered Nonanuclear Ni(II) Cluster [Elektronische Daten] [Cui Wang, Hai Li, Xiao Zhang, Yi Jiang, Shu Zhang] A novel nonanuclear nickel cluster [Ni9(HL)6(μ 3-OH)6(μ 6-CO3)2(H2O)6]·3H2O·(OH)2(1) (H2L=3-(Pyridine-3-sulfonylamino)-propionic acid) has been synthesized and structurally determined by elemental analysis, IR, and X-ray single crystal diffraction. Complex 1 consists of a nonanuclear nickel (II) cage with double μ 6-CO3 2− bridge ant it represents the first nonanuclear nickel (II) cluster whit HL ligand. Magnetic studies indicated that the [Ni9(HL)6(μ 3-OH)6(μ 6-CO3)2(H2O)6]2+ core displays dominant antiferromagnetic interaction between nickel ions. Springer Science+Business Media New York, 2014 Nonanuclear nickel cluster nationallicence Crystal structure nationallicence Magnetic property nationallicence Wang Cui School of Chemistry and Pharmaceutical Sciences (Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China), Guangxi Normal University, 541004, Guilin, People's Republic of China aut Li Hai School of Chemistry and Pharmaceutical Sciences (Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China), Guangxi Normal University, 541004, Guilin, People's Republic of China aut Zhang Xiao School of Chemistry and Pharmaceutical Sciences (Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China), Guangxi Normal University, 541004, Guilin, People's Republic of China aut Jiang Yi School of Chemistry and Pharmaceutical Sciences (Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China), Guangxi Normal University, 541004, Guilin, People's Republic of China aut Zhang Shu College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1055-1065 1040-7278 26:4<1055 2015 26 10876 https://doi.org/10.1007/s10876-014-0796-z text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0796-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Cui School of Chemistry and Pharmaceutical Sciences (Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China), Guangxi Normal University, 541004, Guilin, People's Republic of China aut NATIONALLICENCE 700 1- Li Hai School of Chemistry and Pharmaceutical Sciences (Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China), Guangxi Normal University, 541004, Guilin, People's Republic of China aut NATIONALLICENCE 700 1- Zhang Xiao School of Chemistry and Pharmaceutical Sciences (Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China), Guangxi Normal University, 541004, Guilin, People's Republic of China aut NATIONALLICENCE 700 1- Jiang Yi School of Chemistry and Pharmaceutical Sciences (Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China), Guangxi Normal University, 541004, Guilin, People's Republic of China aut NATIONALLICENCE 700 1- Zhang Shu College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1055-1065 1040-7278 26:4<1055 2015 26 10876