caa a22 4500 606181660 CHVBK 20210128100812.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0802-5 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0802-5 Syntheses, Structures and Properties of Three New Trinuclear Nickel Clusters with (2-Hydroxy-4-methoxyphenyl)-phenyl-methanone [Elektronische Daten] [Zhehui Weng, Shu-Hua Zhang, Wei Wang, Jing-Jing Guo, Hong Hai] Three new nickel clusters [Ni3(hmpm)4(DMF)2(X)2]·Y (1, X=HCOO−, Y=0; 2, X=CH3COO−; Y=C5H8; 3, X=F3CCOO−, Y=0.5H2O, Hhmpm=(2-hydroxy-4-methoxy-phenyl)-phenyl-methanone) have been prepared via solvothermal method. They were characterized by elemental analysis, IR, UV-Vis, fluorescence and X-ray single-crystal diffraction. All three compounds are defined as trinuclear clusters with three nickel atoms linked in line. Herein, we have used three different carboxylate radicals. The results indicate that the steric hindrance effects in carboxylate radicals do not influence the structures of the clusters. The magnetic investigation shows that complexes 1-3 exhibit a ferromagnetic coupling between NiII ions. Springer Science+Business Media New York, 2014 Trinuclear clusters nationallicence Solvothermal method nationallicence Steric hindrance nationallicence Magnetic properties nationallicence Fluorescence nationallicence Weng Zhehui Department of Chemical Science and Technology, Kunming University, 650214, Kunming, People's Republic of China aut Zhang Shu-Hua College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut Wang Wei College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut Guo Jing-Jing College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut Hai Hong College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1129-1142 1040-7278 26:4<1129 2015 26 10876 https://doi.org/10.1007/s10876-014-0802-5 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0802-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Weng Zhehui Department of Chemical Science and Technology, Kunming University, 650214, Kunming, People's Republic of China aut NATIONALLICENCE 700 1- Zhang Shu-Hua College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut NATIONALLICENCE 700 1- Wang Wei College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut NATIONALLICENCE 700 1- Guo Jing-Jing College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut NATIONALLICENCE 700 1- Hai Hong College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, 541004, Guilin, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1129-1142 1040-7278 26:4<1129 2015 26 10876