caa a22 4500 606181695 CHVBK 20210128100812.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0801-6 doi (NATIONALLICENCE)springer-10.1007/s10876-014-0801-6 Two Novel Fe7Mg8 and Fe8Co7 Cluster-Based 3D Heterometallic Coordination Polymers with H4PMIDA and H3BTC as the Co-ligands: Synthesis, Structures, and Fluorescent Properties [Elektronische Daten] [Ai-Qin Zhang, Jie Wang, Li-Jun Qiao, Zhi-Hong Liu] Two novel Fe7Mg8 and Fe8Co7 cluster-based 3D heterometallic coordination polymers, [Fe7Mg8(PMIDA)6(BTC)2(H2O)12]·6H2O(1) and [Fe8Co7(PMIDA)6(BTC)2(H2O)12]·6H2O(2), constructed by multifunctional H4PMIDA (N-(Phosphonomethyl)imino-diacetic acid) and H3BTC(1,3,5-benzenetricarboxylate acid) as the co-ligands, have been synthesized under hydrothermal conditions, and characterized by elemental analysis, IR spectrum, powder X-ray diffraction, thermal analysis and single-crystal X-ray diffraction. The complexes 1 and 2 are basically isostructural and feature a cubic 3D open framework constructed by [M15(PMIDA)6(H2O)12]] (M15=Fe7Mg8 for 1 and Fe8Co7 for 2) heteronuclear clusters and BTC3− ligands. Moreover, the solid-state fluorescence properties of the complexes have also been investigated at room temperature. Springer Science+Business Media New York, 2014 Heteronuclear clusters nationallicence Mixture ligands nationallicence Synthesis nationallicence Crystal structure nationallicence Fluorescent property nationallicence Zhang Ai-Qin Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut Wang Jie Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut Qiao Li-Jun Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut Liu Zhi-Hong Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1115-1127 1040-7278 26:4<1115 2015 26 10876 https://doi.org/10.1007/s10876-014-0801-6 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0801-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhang Ai-Qin Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut NATIONALLICENCE 700 1- Wang Jie Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut NATIONALLICENCE 700 1- Qiao Li-Jun Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut NATIONALLICENCE 700 1- Liu Zhi-Hong Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, 710062, Xi'an, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1115-1127 1040-7278 26:4<1115 2015 26 10876