caa a22 4500 606181709 CHVBK 20210128100812.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0817-y doi (NATIONALLICENCE)springer-10.1007/s10876-014-0817-y Solvothermal Syntheses and Characterization of Three New Thioantimonates Combined with Lanthanide Complexes [Elektronische Daten] [Ligang Zhu, Xing Liu, Jian Zhou, Liu Yang, Rongqing Zhao, Yu Hui, Shimei Tang] Three lanthanide thioantimonates [Ho(en)4]SbVS4·0.5en (1, en=ethylenediamine) and [Ln(teta)(en)SbVS4] [Ln=Ho (2), Y (3), teta=triethylenetetramine] were prepared under mild solvothermal conditions and structurally characterized. 1 consists of isolated [Ho(en)4]3+ ion, tetrahedral [SbVS4]3− ion, and free en molecule. Both 2 and 3 contain neutral lanthanide-centred complex, where the tetrahedral anion [SbVS4]3− acts as a chelating ligand to complex [Ln(en)(teta)]3+ cation. Density functional theory calculations for both 2 and 3 have been performed, and the band gaps of 2.02eV for 1, 1.78eV for 2 and 1.83eV for 3 have been derived from optical absorption. Springer Science+Business Media New York, 2015 Solvothermal synthesis nationallicence Crystal structure nationallicence Thioantimonates nationallicence Lanthanide complexes nationallicence Zhu Ligang College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut Liu Xing College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut Zhou Jian College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut Yang Liu College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut Zhao Rongqing College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut Hui Yu College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut Tang Shimei College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1333-1341 1040-7278 26:4<1333 2015 26 10876 https://doi.org/10.1007/s10876-014-0817-y text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0817-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhu Ligang College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut NATIONALLICENCE 700 1- Liu Xing College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut NATIONALLICENCE 700 1- Zhou Jian College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut NATIONALLICENCE 700 1- Yang Liu College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut NATIONALLICENCE 700 1- Zhao Rongqing College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut NATIONALLICENCE 700 1- Hui Yu College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut NATIONALLICENCE 700 1- Tang Shimei College of Chemistry, Chongqing Normal University, 401331, Chongqing, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1333-1341 1040-7278 26:4<1333 2015 26 10876