caa a22 4500 606181776 CHVBK 20210128100812.0 cr unu---uuuuu 210128e20150701xx s 000 0 eng 10.1007/s10876-014-0824-z doi (NATIONALLICENCE)springer-10.1007/s10876-014-0824-z Metal Oxygen Connectivities in Cu(II) Complexes of Meso-2,3-dibromosuccinic Acid (H2DBrS): [Cu3(H2O)2( μ 3-OH)2( μ 2-OAc)2(DBrS)]⋅4H2O 1 and [Cu3(H2O)4(DBrS)2](DBrSM)⋅4H2O 2 [Elektronische Daten] [Wan-Dan Weng, Yue-Qing Zheng, Feng Jiang, Qing-Jun Niu, Hong-Lin Zhu] Two metal oxygen connectivities Cu(II) complexes [Cu3(H2O)2(μ 3-OH)2(μ 2-OAc)2(DBrS)]⋅4H2O 1 and [Cu3(H2O)4(DBrS)2](DBrSM)⋅4H2O 2 have been synthesized (H2DBrS=HOOC-(CHBr)2-COOH, DBrSM=(3aR,6aS)-3a,6a-dibromo-3,6-dioxohexahydrofuro[3,4-c]furan-1,4-bis(olate)). Within 1, two CuO5 square pyramid are edge-shared to generate di-square pyramids, each of which are corner-shared to one another CuO6 octahedron to form polyhedral copper oxygen chains. The resulted polynuclear single chains are bridged by meso-2,3-dibromossuccinate anions to generate 2D layers. Compound 2 features a trimer polyhedrons unit with two CuO5 square pyramid and CuO6 octahedron, which are further interconnected by meso-2,3-dibromossuccinate anions into 3D coordination polymer. The study of magnetic property indicates that antiferromagnetic coupling interactions exist between the adjacent Cu(II) ions. Springer Science+Business Media New York, 2014 Copper nationallicence Metal oxygen connectivity nationallicence Meso-2,3-dibromosuccinic acid nationallicence Coordination polymer nationallicence Topology nationallicence Weng Wan-Dan Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut Zheng Yue-Qing Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut Jiang Feng Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut Niu Qing-Jun Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut Zhu Hong-Lin Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1425-1438 1040-7278 26:4<1425 2015 26 10876 https://doi.org/10.1007/s10876-014-0824-z text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-014-0824-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Weng Wan-Dan Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut NATIONALLICENCE 700 1- Zheng Yue-Qing Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut NATIONALLICENCE 700 1- Jiang Feng Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut NATIONALLICENCE 700 1- Niu Qing-Jun Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut NATIONALLICENCE 700 1- Zhu Hong-Lin Crystal Engineering Lab, Research Center for Solid State Chemistry & Application, Ningbo University, 315211, Ningbo, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/4(2015-07-01), 1425-1438 1040-7278 26:4<1425 2015 26 10876