caa a22 4500 606181830 CHVBK 20210128100812.0 cr unu---uuuuu 210128e20150901xx s 000 0 eng 10.1007/s10876-015-0840-7 doi (NATIONALLICENCE)springer-10.1007/s10876-015-0840-7 [Pb(en)0.5][B5O8(OH)]: A New Bilayered Organic-Inorganic Hybrid Lead Borate Built by B5O8(OH) Cluster Units [Elektronische Daten] [Lan Ma, Huan He, Bai-Feng Yang, Qiang Zhang, Guo-Yu Yang] A new layered organic-inorganic hybrid lead borate [Pb(en)0.5][B5O8(OH)] (1, en=ethylenediamine), has been hydro(solvo)thermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy and thermogravimetric analysis, respectively. Compound 1 crystallizes in triclinic system space group P-1 (No. 2), a=6.6537(6)Å, b=6.7157(6)Å, c=10.6911(9)Å, α=99.015(7)°, β=93.657(7)°, γ=118.915(9)°, V=407.59(6)Å3, Z=2. The structure consists of two infinite borate layers constructed from [B5O8(OH)]2− cluster building units, then two such layers are further connected by the linear [Pb2(en)]4+ complex linkers to form the novel bilayer structure. Springer Science+Business Media New York, 2015 Hydrothermal synthesis nationallicence Crystal structure nationallicence Lead borate nationallicence Oxo boron cluster nationallicence Lead nationallicence Ma Lan MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut He Huan MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut Yang Bai-Feng MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut Zhang Qiang MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut Yang Guo-Yu MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1495-1502 1040-7278 26:5<1495 2015 26 10876 https://doi.org/10.1007/s10876-015-0840-7 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0840-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ma Lan MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 700 1- He Huan MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 700 1- Yang Bai-Feng MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 700 1- Zhang Qiang MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 700 1- Yang Guo-Yu MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1495-1502 1040-7278 26:5<1495 2015 26 10876