caa a22 4500 60618189X CHVBK 20210128100813.0 cr unu---uuuuu 210128e20150901xx s 000 0 eng 10.1007/s10876-015-0878-6 doi (NATIONALLICENCE)springer-10.1007/s10876-015-0878-6 Two Zincoborates Built by Metal-Nonmetal {Zn2B} Hybrid Clusters [Elektronische Daten] [Ang Yin, Wei-Hui Fang, Qi Wei, Guo-Yu Yang] Two novel layered zincoborates, [HN(C2H5)3]2[Zn4B2(C4H2O6)4(H2O)3]·0.5H2O (1) and [HN(C2H5)3][Zn2B(C4H2O6)2(H2O)] (2), have been synthesized under mild solvothermal conditions. Both compounds are characterized by single-crystal X-ray diffraction, powder X-ray diffraction, IR spectroscopy and elemental analysis, respectively. Structure analyses reveal that they possess the same metal-nonmetal hybrid Zn2B(C4H2O6)2 {Zn2B} cluster building units (CBUs). These CBUs connect with tartaric acid into linear chains. The different orientation and arrangements of the chains lead to the formation of two sorts of topologically similar corrugated layers. Furthermore, the thermal analyses and semiconducting behaviors were performed. Springer Science+Business Media New York, 2015 Zincoborate nationallicence Tartrate nationallicence Solvothermal synthesis nationallicence Crystal structure nationallicence Semiconductivity nationallicence Yin Ang College of Chemistry, Fuzhou University, 350108, Fuzhou, Fujian, People's Republic of China aut Fang Wei-Hui State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, People's Republic of China aut Wei Qi State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, People's Republic of China aut Yang Guo-Yu College of Chemistry, Fuzhou University, 350108, Fuzhou, Fujian, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1801-1809 1040-7278 26:5<1801 2015 26 10876 https://doi.org/10.1007/s10876-015-0878-6 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0878-6 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yin Ang College of Chemistry, Fuzhou University, 350108, Fuzhou, Fujian, People's Republic of China aut NATIONALLICENCE 700 1- Fang Wei-Hui State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, People's Republic of China aut NATIONALLICENCE 700 1- Wei Qi State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002, Fuzhou, Fujian, People's Republic of China aut NATIONALLICENCE 700 1- Yang Guo-Yu College of Chemistry, Fuzhou University, 350108, Fuzhou, Fujian, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1801-1809 1040-7278 26:5<1801 2015 26 10876