caa a22 4500 606181911 CHVBK 20210128100813.0 cr unu---uuuuu 210128e20150901xx s 000 0 eng 10.1007/s10876-015-0884-8 doi (NATIONALLICENCE)springer-10.1007/s10876-015-0884-8 Two Distinct Dimeric Heterothiometallic W/S/Cu Clusters with Effective Photocatalystic Property [Elektronische Daten] [Jinfang Zhang, Chao Wang, Chi Zhang] Two heterothiometallic W/S/Cu dimeric clusters, {[WS4Cu4Cl2(phen)2]2·MeCN} (1) and {[CuCl(phen)2]2[WOS3Cu3Cl2(phen)]2} (2), were synthesized by the reactions of 1,10-phenanthroline (phen), CuCl and (NH4)2WS4 or (NH4)2WOS3, in DMF. 1 and 2 were characterized by elemental analyses, IR, UV-Vis, X-ray powder and single crystal diffractions. 1 exhibits a rare dimeric architecture, constructed by two parallel pentanuclear planar ‘open' [WS4Cu4Cl2(phen)2] clusters linked together via a pair of μ 2-Cl bridges. While 2 consists of the five-coordinated cation [CuCl(phen)2]+ and the dimeric anionic cluster {[WOS3Cu3Cl2(phen)]2}2−, which is fabricated by a pair of tetranuclear nest-shaped clusters, connected by two μ 2-Cl bridges. Moreover, the photocatalytic activities of heterothiometallic clusters were firstly explored by monitoring the photodegradation of methylene blue (MB), which reveals that 1 and 2 both exhibit effective photocatalytic properties under Xe-illuminator irradiation. Springer Science+Business Media New York, 2015 Heterothiometallic W/S/Cu clusters nationallicence Dimeric architectures nationallicence Photocatalysis nationallicence Zhang Jinfang China-Australia Joint Research Center for Functional Molecular Materials, School of Chemical and Material Engineering, Jiangnan University, 214122, Wuxi, People's Republic of China aut Wang Chao China-Australia Joint Research Center for Functional Molecular Materials, School of Chemical and Material Engineering, Jiangnan University, 214122, Wuxi, People's Republic of China aut Zhang Chi China-Australia Joint Research Center for Functional Molecular Materials, School of Chemical and Material Engineering, Jiangnan University, 214122, Wuxi, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1857-1872 1040-7278 26:5<1857 2015 26 10876 https://doi.org/10.1007/s10876-015-0884-8 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0884-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Zhang Jinfang China-Australia Joint Research Center for Functional Molecular Materials, School of Chemical and Material Engineering, Jiangnan University, 214122, Wuxi, People's Republic of China aut NATIONALLICENCE 700 1- Wang Chao China-Australia Joint Research Center for Functional Molecular Materials, School of Chemical and Material Engineering, Jiangnan University, 214122, Wuxi, People's Republic of China aut NATIONALLICENCE 700 1- Zhang Chi China-Australia Joint Research Center for Functional Molecular Materials, School of Chemical and Material Engineering, Jiangnan University, 214122, Wuxi, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1857-1872 1040-7278 26:5<1857 2015 26 10876