caa a22 4500 60618192X CHVBK 20210128100813.0 cr unu---uuuuu 210128e20150901xx s 000 0 eng 10.1007/s10876-015-0880-z doi (NATIONALLICENCE)springer-10.1007/s10876-015-0880-z New Member of Organic Ligand Functionalized TMSP: Synthesis, Characterized and Properties of Na15[(MnII(COOH))3(AsW9O33)2]·15H2O [Elektronische Daten] [Qiong Wu, Hongping Ju, Jian Tao, Zihao Chen, Jun Li, Fuyan Wang, Qian Cai, Lifen Sun, Xinghua Pan] Reaction of [Mn12(CH3COO)16(H2O)4O12]·2CH3COOH·4H2O and Na9[AsW9O33]·19.5H2O in aqueous solution leads to the isolation of a new carboxy group decorated TMSP, Na15[(MnII(COOH))3(AsW9O33)2]·15H2O (1). The structure of 1 was characterized by elemental analysis, thermometric analysis and single crystal X-ray diffraction (Crystal data for 1: Trigonal, P-3, a=12.8804(4)Å, b=12.8804(4)Å, c=30.3501(19)Å, V=4360.6(3)Å3, Z=2). Structural analysis reveals that 1 represents the first example of carboxy group decorated arsenotungstate. Antitumor study indicates that compound 1 possesses high antitumor activity against Hela cells. In addition, the magnetic properties of 1 were also investigated. Springer Science+Business Media New York, 2015 Polyoxometalate nationallicence Arsenotungstate nationallicence Organic ligand nationallicence Antitumor activity nationallicence Magnetic properties nationallicence Wu Qiong Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Ju Hongping Medical School, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Tao Jian Medical School, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Chen Zihao Hebei Medical University, 050017, Shijiazhuang, Hebei, People's Republic of China aut Li Jun Medical School, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Wang Fuyan Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Cai Qian Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Sun Lifen Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut Pan Xinghua Stem Cell, Tissue and Organ Engineering Research Center, Kunming General, Hospital of Chinese People's Liberation Army, 650032, Kunming, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1811-1820 1040-7278 26:5<1811 2015 26 10876 https://doi.org/10.1007/s10876-015-0880-z text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0880-z text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wu Qiong Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Ju Hongping Medical School, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Tao Jian Medical School, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Chen Zihao Hebei Medical University, 050017, Shijiazhuang, Hebei, People's Republic of China aut NATIONALLICENCE 700 1- Li Jun Medical School, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Wang Fuyan Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Cai Qian Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Sun Lifen Department of Chemical Science and Technology, Kunming University, 65200, Kunming, Yunnan, People's Republic of China aut NATIONALLICENCE 700 1- Pan Xinghua Stem Cell, Tissue and Organ Engineering Research Center, Kunming General, Hospital of Chinese People's Liberation Army, 650032, Kunming, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1811-1820 1040-7278 26:5<1811 2015 26 10876