caa a22 4500 606182063 CHVBK 20210128100814.0 cr unu---uuuuu 210128e20150901xx s 000 0 eng 10.1007/s10876-015-0843-4 doi (NATIONALLICENCE)springer-10.1007/s10876-015-0843-4 Synthesis, Structure and Fluorescent Property of a New Isolated Co6Mg9 Heteronuclear Cluster [Elektronische Daten] [Xiao-Lan Wang, Jun-Feng Wang] A novel zero-dimensional Co6Mg9 heteronuclear cluster based on N-(phosphonomethyl)imino-diacetic acid (H4PMIDA) and 1,3,5-benzenetricarboxylate acid (H3BTC) multifunctional ligands, [Co6Mg9(PMIDA)6(H2O)24]·(BTC)2·22H2O (1), has been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectra, thermal analyses, and single-crystal X-ray diffraction. The complex 1 exhibits a isolated cationic 15 heteronuclear cluster [Co6Mg9(PMIDA)6(H2O)24]6+, and its charges are balanced by two anionic BTC3−. Each isolated cluster is further extended into a 3D supramolecular network through very extensive O-H···O hydrogen bonds. Moreover, the solid-state fluorescent property of the complex 1 has also been investigated at room temperature. Springer Science+Business Media New York, 2015 Isolated heteronuclear cluster nationallicence Phosphonic acid nationallicence Synthesis nationallicence Crystal structure nationallicence Fluorescent property nationallicence Wang Xiao-Lan Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, 710100, Xi'an, People's Republic of China aut Wang Jun-Feng Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, 710100, Xi'an, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1527-1535 1040-7278 26:5<1527 2015 26 10876 https://doi.org/10.1007/s10876-015-0843-4 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0843-4 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Xiao-Lan Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, 710100, Xi'an, People's Republic of China aut NATIONALLICENCE 700 1- Wang Jun-Feng Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, 710100, Xi'an, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1527-1535 1040-7278 26:5<1527 2015 26 10876