caa a22 4500 60618211X CHVBK 20210128100814.0 cr unu---uuuuu 210128e20150901xx s 000 0 eng 10.1007/s10876-015-0881-y doi (NATIONALLICENCE)springer-10.1007/s10876-015-0881-y Decavanadate Cage-like Cluster Templated by Organic Counter Cation: Synthesis, Characterization and Its Antimicrobial Effect Against Gram Positive E. Feacium [Elektronische Daten] [Sirine Toumi, Nicolas Ratel-Ramond, Samah Akriche] Decavanadate cluster templated with organic cation, [4-(CH3O)C6H4CH2NH3]6V10O28·2H2O (4MBAV10) has been prepared and characterized by elemental analysis, X-ray diffraction and IR., UV-Vis., fluorescence and 1H, 13C-NMR spectroscopies. The X-ray structure determination revealed the discrete decavanadate cage-like clusters [V10O28]6− (V10). These polymeric species associated to lattice water results into inorganic 2D-framework $$ \left[ {{\text{V}}_{ 10} {\text{O}}_{ 2 8} \left( {{\text{H}}_{ 2} {\text{O}}} \right)_{ 4} } \right]_{\text{n}}^{6 - } $$ V 10 O 28 H 2 O 4 n 6 - stacked parallel to the (a,b) plane where the templating cations filled the interlayer spacing to perform 3D supramolecular network supported by a set of O-H···O, N-H···O, C-H···O and C-H···π interactions as well as electrostatic ones. The optical survey of 4MBAV10 has been used to determine the optical band gap and to provide the blue fluorescent behavior of grown crystals. Furthermore, antibacterial activity was tested and showed that the compound exhibited a reasonable activity against gramm positif Enterococcus feacium. Graphical Abstract: Springer Science+Business Media New York, 2015 Decavanadate nationallicence Synthesis nationallicence Single-crystal XRD nationallicence Fluorescence nationallicence Antibacterial activity nationallicence Toumi Sirine Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, 7021 Zarzouna, Bizerte, Tunisia aut Ratel-Ramond Nicolas CEMES-CNRS, 29 rue Jeanne Marvig, 31055, Toulouse Cedex 4, France aut Akriche Samah Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, 7021 Zarzouna, Bizerte, Tunisia aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1821-1831 1040-7278 26:5<1821 2015 26 10876 https://doi.org/10.1007/s10876-015-0881-y text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0881-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Toumi Sirine Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, 7021 Zarzouna, Bizerte, Tunisia aut NATIONALLICENCE 700 1- Ratel-Ramond Nicolas CEMES-CNRS, 29 rue Jeanne Marvig, 31055, Toulouse Cedex 4, France aut NATIONALLICENCE 700 1- Akriche Samah Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, 7021 Zarzouna, Bizerte, Tunisia aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1821-1831 1040-7278 26:5<1821 2015 26 10876