caa a22 4500 606182128 CHVBK 20210128100814.0 cr unu---uuuuu 210128e20150901xx s 000 0 eng 10.1007/s10876-015-0845-2 doi (NATIONALLICENCE)springer-10.1007/s10876-015-0845-2 Two New Borates Containing [B5O6(OH)4] Clusters, Accompanying a Novel In Situ Organic Reaction Between Ethylenediamine and CH3COO− Group [Elektronische Daten] [Yuan Liu, Huan He, Bai-Feng Yang, Qiang Zhang, Guo-Yu Yang] Two new borate clusters, [C4H11N2O][C4H9N2][B5O6(OH)4]2 (1), [Cd(dien)2][B5O6(OH)4]2 (2, dien=diethylenetriamine), have been obtained under solvothermal conditions and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray structural analysis, respectively. Crystal data for 1: monoclinic, P21/c, a=18.6975(5)Å, b=15.3413(8)Å, c=9.6691(3)Å, β=90.462(3)°, Z=4. Crystal data for 2: triclinic, P-1, a=8.6107(4)Å, b=9.3504(4)Å, c=18.9631(4)Å, α=103.798(4), β=91.940(4)°, γ=94.134(4)°, Z=2. They all consist of [B5O6(OH)4]− clusters and further extend to 3-D frameworks via extensive hydrogen-bonding interactions. Interestingly, a novel in situ organic reaction between ethylenediamine and CH3COO− group has been observed during the formation of compound 1. Springer Science+Business Media New York, 2015 Borates nationallicence Solvothermal synthesis nationallicence In situ reaction nationallicence Crystal structure nationallicence Amine nationallicence Liu Yuan MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut He Huan MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut Yang Bai-Feng MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut Zhang Qiang MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut Yang Guo-Yu MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1537-1545 1040-7278 26:5<1537 2015 26 10876 https://doi.org/10.1007/s10876-015-0845-2 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0845-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Liu Yuan MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 700 1- He Huan MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 700 1- Yang Bai-Feng MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 700 1- Zhang Qiang MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 700 1- Yang Guo-Yu MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, 100081, Beijing, China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1537-1545 1040-7278 26:5<1537 2015 26 10876