caa a22 4500 606182144 CHVBK 20210128100814.0 cr unu---uuuuu 210128e20150901xx s 000 0 eng 10.1007/s10876-015-0858-x doi (NATIONALLICENCE)springer-10.1007/s10876-015-0858-x A New 2D Network Constructed from the Extension of Transition-Metal-Grafted ε-Keggin Polyoxoanion by a Bridging Organic Carboxylate [Elektronische Daten] [Bao-Xia Dong, Lu Chen, Shi-Yang Zhang, Yi-Chen Wu, Hui Tian, Jun Ge, Liang Song, Yun-Lei Teng, Wen-Long Liu] By introducing a bridging ligand of 5-methylisophthalic acid (shortened as 5-mip) into the tetrahedral Zn4-ε-Keggin system, a new 2D network of [TBA]3[H4PMo 8 V Mo 4 VI O40Zn4][C7H6(COO)2]2 (1) was synthesized under hydrothermal condition. It was characterized by FT-IR, BET, TGA/DSC-MASS analysis, powder X-ray diffraction and single-crystal X-ray diffraction, respectively. Besides, compound 1 shows remarkable electrocatalytic activity towards bromate reduction. Springer Science+Business Media New York, 2015 Polyoxometalate nationallicence ε-Keggin nationallicence POMOFs nationallicence Electrocatalyst nationallicence Bromate nationallicence Dong Bao-Xia College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut Chen Lu College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut Zhang Shi-Yang College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut Wu Yi-Chen College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut Tian Hui College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut Ge Jun College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut Song Liang College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut Teng Yun-Lei College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut Liu Wen-Long College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1595-1605 1040-7278 26:5<1595 2015 26 10876 https://doi.org/10.1007/s10876-015-0858-x text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10876-015-0858-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Dong Bao-Xia College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Chen Lu College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Zhang Shi-Yang College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Wu Yi-Chen College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Tian Hui College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Ge Jun College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Song Liang College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Teng Yun-Lei College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Liu Wen-Long College of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Cluster Science Springer US; http://www.springer-ny.com 26/5(2015-09-01), 1595-1605 1040-7278 26:5<1595 2015 26 10876