caa a22 4500 606194819 CHVBK 20210128100916.0 cr unu---uuuuu 210128e20150201xx s 000 0 eng 10.1007/s10934-014-9883-7 doi (NATIONALLICENCE)springer-10.1007/s10934-014-9883-7 Size and morphological control of a metal-organic framework Cu-BTC by variation of solvent and modulator [Elektronische Daten] [E. Sanil, Kyung-Ho Cho, Su-Kyung Lee, U-Hwang Lee, Sam Ryu, Hae Lee, Jong-San Chang, Young Hwang] A metal-organic framework of copper 1,3,5-benzenetricarboxylate (Cu-BTC) has been synthesized using the microwave-assisted method, with different solvents. Synthesized compounds were washed repeatedly with a mixture of deionized water and ethanol to ensure the removal of impurities. Finally, purified samples were characterized using XRD and SEM to understand their morphological and structural features. The effect of solvent and modulator (dodecanoic acid) on the crystallinity and morphology of synthesized particles was investigated. The crystallinity depends on the dielectric constant and dielectric loss factor of the solvent used. The Cu-BTC crystals synthesized using ethylene glycol at low concentration [mole ratio of copper salt (1) to ethylene glycol (180)] were octahedral, but increasing the concentration [mole ratio of copper salt (1) to ethylene glycol (36)] changed the crystal morphology from octahedral to hexagonal. Interestingly, a dramatic change in the particle size and morphology was observed for Cu-BTC synthesized using ethylene glycol with coordination modulator. Springer Science+Business Media New York, 2014 MOF materials nationallicence Cu-BTC nationallicence Solvent effect nationallicence Microwave synthesis nationallicence Sanil E. Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut Cho Kyung-Ho Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut Lee Su-Kyung Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut Lee U-Hwang Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut Ryu Sam Agency for Defense Development, P.O.box 35-52, 305-600, Yuseong, Daejeon, Korea aut Lee Hae Agency for Defense Development, P.O.box 35-52, 305-600, Yuseong, Daejeon, Korea aut Chang Jong-San Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut Hwang Young Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut Journal of Porous Materials Springer US; http://www.springer-ny.com 22/1(2015-02-01), 171-178 1380-2224 22:1<171 2015 22 10934 https://doi.org/10.1007/s10934-014-9883-7 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10934-014-9883-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sanil E. Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut NATIONALLICENCE 700 1- Cho Kyung-Ho Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut NATIONALLICENCE 700 1- Lee Su-Kyung Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut NATIONALLICENCE 700 1- Lee U-Hwang Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut NATIONALLICENCE 700 1- Ryu Sam Agency for Defense Development, P.O.box 35-52, 305-600, Yuseong, Daejeon, Korea aut NATIONALLICENCE 700 1- Lee Hae Agency for Defense Development, P.O.box 35-52, 305-600, Yuseong, Daejeon, Korea aut NATIONALLICENCE 700 1- Chang Jong-San Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut NATIONALLICENCE 700 1- Hwang Young Catalysis Center for Molecular Engineering (CCME), Korea Research Institute of Chemical Technology (KRICT), Shinseongno 17, 305-600, Yusung, Daejeon, Korea aut NATIONALLICENCE 773 0- Journal of Porous Materials Springer US; http://www.springer-ny.com 22/1(2015-02-01), 171-178 1380-2224 22:1<171 2015 22 10934