caa a22 4500 606195106 CHVBK 20210128100917.0 cr unu---uuuuu 210128e20151201xx s 000 0 eng 10.1007/s10934-015-0039-1 doi (NATIONALLICENCE)springer-10.1007/s10934-015-0039-1 Synthesis of catalytically active porous organic polymer from iron phthalocyanine and diimide building blocks [Elektronische Daten] [Pan Ma, Liang Lv, Min Zhang, Qing Yuan, Jiantao Cao, Changhua Zhu] A novel diimide-linked, iron(III) containing porous organic polymer (FePPOP) was designed and synthesized by the raise-by-one-story method using iron(III)tetraaminophthalocyanine and 3,4,9,10-perylene tetracarboxylic dianhydride. The yielded polymer has been fully characterized by IR, X-ray diffraction, scanning electron microscopy, thermal gravimetric analysis and nitrogen sorption isotherm measurements. FePPOP has unique morphological properties e.g. amorphous, insoluble, multilayered microporous structure. It also served as an efficient heterogeneous catalyst in the oxidation reaction of benzyl alcohol to benzaldehyde under mild reaction condition with a large turnover number as high as 960. The present work showcased a group of structure-function relationship among molecular structure, porous organic polymer structure, and catalyst functional properties. It would attract great research interest in the catalysis applications of a new class of porous organic polymers in organic reactions. Springer Science+Business Media New York, 2015 Phthalocyanine nationallicence Porous organic polymer nationallicence Heterogeneous catalysis nationallicence Turnover number (TON) nationallicence Ma Pan College of Resource and Environment, Shandong Agricultural University, 271018, Tai'an, People's Republic of China aut Lv Liang Test Center for Agri-Product Quality of Jinan, 250316, Jinan, People's Republic of China aut Zhang Min College of Resource and Environment, Shandong Agricultural University, 271018, Tai'an, People's Republic of China aut Yuan Qing Test Center for Agri-Product Quality of Jinan, 250316, Jinan, People's Republic of China aut Cao Jiantao Test Center for Agri-Product Quality of Jinan, 250316, Jinan, People's Republic of China aut Zhu Changhua Jinan Academy of Agricultural Sciences, 250316, Jinan, People's Republic of China aut Journal of Porous Materials Springer US; http://www.springer-ny.com 22/6(2015-12-01), 1567-1571 1380-2224 22:6<1567 2015 22 10934 https://doi.org/10.1007/s10934-015-0039-1 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10934-015-0039-1 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ma Pan College of Resource and Environment, Shandong Agricultural University, 271018, Tai'an, People's Republic of China aut NATIONALLICENCE 700 1- Lv Liang Test Center for Agri-Product Quality of Jinan, 250316, Jinan, People's Republic of China aut NATIONALLICENCE 700 1- Zhang Min College of Resource and Environment, Shandong Agricultural University, 271018, Tai'an, People's Republic of China aut NATIONALLICENCE 700 1- Yuan Qing Test Center for Agri-Product Quality of Jinan, 250316, Jinan, People's Republic of China aut NATIONALLICENCE 700 1- Cao Jiantao Test Center for Agri-Product Quality of Jinan, 250316, Jinan, People's Republic of China aut NATIONALLICENCE 700 1- Zhu Changhua Jinan Academy of Agricultural Sciences, 250316, Jinan, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Porous Materials Springer US; http://www.springer-ny.com 22/6(2015-12-01), 1567-1571 1380-2224 22:6<1567 2015 22 10934