caa a22 4500 606195238 CHVBK 20210128100918.0 cr unu---uuuuu 210128e20150601xx s 000 0 eng 10.1007/s10934-015-9947-3 doi (NATIONALLICENCE)springer-10.1007/s10934-015-9947-3 The catalytic performance of Ti-PILC supported CrOx-CeO2 catalysts for n -butylamine oxidation [Elektronische Daten] [Zhinan Shi, Qinqin Huang, Peng Yang, Renxian Zhou] A series of titanium pillared clays (Ti-PILC) materials are synthesized by different preparation conditions and the influence of the texture/structure nature of Ti-PILC on the catalytic performance of Ti-PILC supported CrOx-CeO2 mixed oxide (CrCe/Ti-PILC) catalysts for n-butylamine oxidation is investigated. The titanium pillared clays materials possess larger specific surface area and abundant porous structure with some irregular pore channel and nonuniform pore size distribution, due to the collapse of layered structure during pillaring process. The preparation conditions have significant impact on texture/structure properties of Ti-PILC. The synergistic effect between CrOx-CeO2 and Ti-PILC supports is promoted due to outstanding texture/structure properties of Ti-PILC, which enhances the catalytic activity for n-butylamine oxidation over Ti-PILC supported CrOx-CeO2 catalysts, especially for the 8CrCe(6:1)/Ti-PILC(12,20) catalyst. All the catalysts show a good control quality of NOx, and the yield of NOx is limited within 1% at T98. Springer Science+Business Media New York, 2015 Titanium pillared clays (Ti-PILC) nationallicence Supported CrOx-CeO2 catalysts nationallicence N -butylamine nationallicence Catalytic oxidation nationallicence Porous structure nationallicence Shi Zhinan Institute of Catalysis, Zhejiang University, 310028, Hangzhou, People's Republic of China aut Huang Qinqin Research Institute of Petrochemical Technology, 201208, Shanghai, People's Republic of China aut Yang Peng Institute of Catalysis, Zhejiang University, 310028, Hangzhou, People's Republic of China aut Zhou Renxian Institute of Catalysis, Zhejiang University, 310028, Hangzhou, People's Republic of China aut Journal of Porous Materials Springer US; http://www.springer-ny.com 22/3(2015-06-01), 739-747 1380-2224 22:3<739 2015 22 10934 https://doi.org/10.1007/s10934-015-9947-3 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10934-015-9947-3 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Shi Zhinan Institute of Catalysis, Zhejiang University, 310028, Hangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Huang Qinqin Research Institute of Petrochemical Technology, 201208, Shanghai, People's Republic of China aut NATIONALLICENCE 700 1- Yang Peng Institute of Catalysis, Zhejiang University, 310028, Hangzhou, People's Republic of China aut NATIONALLICENCE 700 1- Zhou Renxian Institute of Catalysis, Zhejiang University, 310028, Hangzhou, People's Republic of China aut NATIONALLICENCE 773 0- Journal of Porous Materials Springer US; http://www.springer-ny.com 22/3(2015-06-01), 739-747 1380-2224 22:3<739 2015 22 10934