caa a22 4500 606196064 CHVBK 20210128100922.0 cr unu---uuuuu 210128e20150401xx s 000 0 eng 10.1007/s10934-014-9901-9 doi (NATIONALLICENCE)springer-10.1007/s10934-014-9901-9 Application of mesoporous ZSM-5 as a support for Fischer-Tropsch cobalt catalysts [Elektronische Daten] [Yuelun Wang, Weiming Zhao, Zhuo Li, Hui Wang, Jinhu Wu, Min Li, Zhiping Hu, Yongshen Wang, Jun Huang, Yunpeng Zhao] The effect of mesoporous structure of ZSM-5 on the properties of cobalt-based catalysts for Fischer-Tropsch synthesis was studied in this work. ZSM-5 and amorphous SiO2 supports have also been applied for comparison. It was shown that post treatment of ZSM-5 catalyst by NaOH solution improved the catalytic performance to produce higher amount of liquid hydrocarbons. The hierarchical structure combining with the acidity of meso-ZSM-5 had great effect on increasing the selectivity to C5-18 hydrocarbons and preventing the formation of CH4. The more acid sites of the support promoted catalytic cracking reaction of olefinic hydrocarbons to light hydrocarbons, the lower olefin to paraffin ratio was observed over Co/meso-ZSM-5 catalyst compared with that of Co/SiO2 catalyst. Springer Science+Business Media New York, 2014 Fischer-Tropsch synthesis nationallicence NaOH treatment nationallicence Mesoporous ZSM-5 nationallicence Cobalt catalyst nationallicence Wang Yuelun Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut Zhao Weiming Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut Li Zhuo Key Laboratory of Biofuel, Chinese Academy of Sciences, Qingdao Institute of Bioenergy and Bioprocess Technology, 266101, Qingdao, China aut Wang Hui Key Laboratory of Biofuel, Chinese Academy of Sciences, Qingdao Institute of Bioenergy and Bioprocess Technology, 266101, Qingdao, China aut Wu Jinhu Key Laboratory of Biofuel, Chinese Academy of Sciences, Qingdao Institute of Bioenergy and Bioprocess Technology, 266101, Qingdao, China aut Li Min Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut Hu Zhiping Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut Wang Yongshen Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut Huang Jun Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut Zhao Yunpeng Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut Journal of Porous Materials Springer US; http://www.springer-ny.com 22/2(2015-04-01), 339-345 1380-2224 22:2<339 2015 22 10934 https://doi.org/10.1007/s10934-014-9901-9 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10934-014-9901-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Wang Yuelun Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut NATIONALLICENCE 700 1- Zhao Weiming Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut NATIONALLICENCE 700 1- Li Zhuo Key Laboratory of Biofuel, Chinese Academy of Sciences, Qingdao Institute of Bioenergy and Bioprocess Technology, 266101, Qingdao, China aut NATIONALLICENCE 700 1- Wang Hui Key Laboratory of Biofuel, Chinese Academy of Sciences, Qingdao Institute of Bioenergy and Bioprocess Technology, 266101, Qingdao, China aut NATIONALLICENCE 700 1- Wu Jinhu Key Laboratory of Biofuel, Chinese Academy of Sciences, Qingdao Institute of Bioenergy and Bioprocess Technology, 266101, Qingdao, China aut NATIONALLICENCE 700 1- Li Min Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut NATIONALLICENCE 700 1- Hu Zhiping Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut NATIONALLICENCE 700 1- Wang Yongshen Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut NATIONALLICENCE 700 1- Huang Jun Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut NATIONALLICENCE 700 1- Zhao Yunpeng Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining and Technology, 221116, Xuzhou, Jiangsu, China aut NATIONALLICENCE 773 0- Journal of Porous Materials Springer US; http://www.springer-ny.com 22/2(2015-04-01), 339-345 1380-2224 22:2<339 2015 22 10934