caa a22 4500 60621724X CHVBK 20210128101107.0 cr unu---uuuuu 210128e20151001xx s 000 0 eng 10.1007/s10598-015-9288-8 doi (NATIONALLICENCE)springer-10.1007/s10598-015-9288-8 Mathematical Modeling of Raft Polymerization [Elektronische Daten] [N. Semendyaeva, S. Kuchanov] A new mathematical model of Reversible Addition-Fragmentation chain Transfer (RAFT) polymerization is proposed, describing a series of experimental data on styrene bulk polymerization in the presence of various RAFT agents. The polymerization slowdown observed with increasing concentration of the RAFT agent is attributable to the accumulation of intermediate products that participate in chain transfers to both low-molecular and polymer RAFT agents, whereas the length of the initiation period is determined entirely by the activity of the low-molecular RAFT agent. Springer Science+Business Media New York, 2015 polymers nationallicence pseudo-living radical polymerization nationallicence RAFT polymerization nationallicence polydispersity nationallicence mathematical modeling nationallicence Semendyaeva N. Faculty of Computational Mathematics and Cybernetics, Moscow State University, Moscow, Russia aut Kuchanov S. Faculty of Computational Mathematics and Cybernetics, Moscow State University, Moscow, Russia aut Computational Mathematics and Modeling Springer US; http://www.springer-ny.com 26/4(2015-10-01), 514-527 1046-283X 26:4<514 2015 26 10598 https://doi.org/10.1007/s10598-015-9288-8 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 research-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s10598-015-9288-8 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Semendyaeva N. Faculty of Computational Mathematics and Cybernetics, Moscow State University, Moscow, Russia aut NATIONALLICENCE 700 1- Kuchanov S. Faculty of Computational Mathematics and Cybernetics, Moscow State University, Moscow, Russia aut NATIONALLICENCE 773 0- Computational Mathematics and Modeling Springer US; http://www.springer-ny.com 26/4(2015-10-01), 514-527 1046-283X 26:4<514 2015 26 10598