caa a22 4500 606218475 CHVBK 20210128101113.0 cr unu---uuuuu 210128e20150201xx s 000 0 eng 10.1007/s11104-014-2251-1 doi (NATIONALLICENCE)springer-10.1007/s11104-014-2251-1 Sparks Donald Interdisciplinary Science and Engineering Lab, University of Delaware, 221 Academy St., Suite 250A, 19716, Newark, DE, USA aut Advances in coupling of kinetics and molecular scale tools to shed light on soil biogeochemical processes [Elektronische Daten] [Donald Sparks] Background: Biogeochemical processes in soils such as sorption, precipitation, and redox play critical roles in the cycling and fate of nutrients, metal(loid)s and organic chemicals in soil and water environments. Advanced analytical tools enable soil scientists to track these processes in real-time and at the molecular scale. Scope: This review focuses on recent research that has employed state-of-the-art molecular scale spectroscopy, coupled with kinetics, to elucidate the mechanisms of nutrient and metal(loid) reactivity and speciation in soils. Conclusions: By coupling kinetics with advanced molecular and nano-scale tools major advances have been made in elucidating important soil chemical processes including sorption, precipitation, dissolution, and redox of metal(loids) and nutrients. Such advances will aid in better predicting the fate and mobility of nutrients and contaminants in soils and water and enhance environmental and agricultural sustainability. Springer International Publishing Switzerland, 2014 Kinetics nationallicence In-situ molecular scale techniques nationallicence Redox nationallicence Sorption nationallicence Surface precipitation nationallicence Light element chemistry nationallicence Plant and Soil Springer International Publishing 387/1-2(2015-02-01), 1-19 0032-079X 387:1-2<1 2015 387 11104 https://doi.org/10.1007/s11104-014-2251-1 text/html Onlinezugriff via DOI BK010053 XK010053 XK010000 Metadata rights reserved Springer special CC-BY-NC licence nationallicence 1 review-article jats NATIONALLICENCE NATIONALLICENCE NL-springer NATIONALLICENCE 856 40 https://doi.org/10.1007/s11104-014-2251-1 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Sparks Donald Interdisciplinary Science and Engineering Lab, University of Delaware, 221 Academy St., Suite 250A, 19716, Newark, DE, USA aut NATIONALLICENCE 773 0- Plant and Soil Springer International Publishing 387/1-2(2015-02-01), 1-19 0032-079X 387:1-2<1 2015 387 11104