Single-point parallel disk correction for asymptotically nonlinear oscillatory shear

Verfasser / Beitragende:
[N. Bharadwaj, Randy Ewoldt]
Ort, Verlag, Jahr:
2015
Enthalten in:
Rheologica Acta, 54/3(2015-03-01), 223-233
Format:
Artikel (online)
ID: 605466513
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024 7 0 |a 10.1007/s00397-014-0824-9  |2 doi 
035 |a (NATIONALLICENCE)springer-10.1007/s00397-014-0824-9 
245 0 0 |a Single-point parallel disk correction for asymptotically nonlinear oscillatory shear  |h [Elektronische Daten]  |c [N. Bharadwaj, Randy Ewoldt] 
520 3 |a We derive exact single-point corrections for parallel disk measurements of all four asymptotically nonlinear measures under strain-controlled oscillatory shear. In this regime, sometimes called medium-amplitude oscillatory shear (MAOS), the derivatives appearing in the general stress correction are constant over the range of interest. This enables an exact single-point correction of all four shear stress components and material functions in the asymptotically nonlinear regime. This greatly simplifies the data processing and allows convenient measurements of true nonlinear material functions with parallel disk geometries. We use a strain amplitude expansion for the stress response, introducing a general non-integer strain amplitude scaling for the leading order nonlinearity, σ ∼ γ α , where typically α = 3 has been assumed in the past. The stress corrections are a multiplicative amplification by a factor f α = α + 3 4 $f\left (\alpha \right )=\frac {\alpha +3}{4}$ , shown for the first time for all four asymptotically nonlinear coefficients. Experimental measurements are presented for the four asymptotically nonlinear signals on an entangled polymer melt of cis-1,4-polyisoprene, using both parallel disk and cone fixtures. The polymer melt follows a cubic (α = 3) strain amplitude scaling in the MAOS regime. The theoretical corrections indicate a 50 % amplification of the apparent signals measured with the parallel disk fixture. The corrected (amplified) signals match the measurements with the cone. 
540 |a Springer-Verlag Berlin Heidelberg, 2015 
690 7 |a Parallel disk rheometry  |2 nationallicence 
690 7 |a Single point correction  |2 nationallicence 
690 7 |a Asymptotically nonlinear rheology  |2 nationallicence 
690 7 |a Large amplitude oscillatory shear  |2 nationallicence 
690 7 |a Uncertainty propagation in MAOS  |2 nationallicence 
690 7 |a MAOS  |2 nationallicence 
700 1 |a Bharadwaj  |D N.  |u Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, 61801, Urbana, IL, USA  |4 aut 
700 1 |a Ewoldt  |D Randy  |u Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, 61801, Urbana, IL, USA  |4 aut 
773 0 |t Rheologica Acta  |d Springer Berlin Heidelberg  |g 54/3(2015-03-01), 223-233  |x 0035-4511  |q 54:3<223  |1 2015  |2 54  |o 397 
856 4 0 |u https://doi.org/10.1007/s00397-014-0824-9  |q text/html  |z Onlinezugriff via DOI 
898 |a BK010053  |b XK010053  |c XK010000 
900 7 |a Metadata rights reserved  |b Springer special CC-BY-NC licence  |2 nationallicence 
908 |D 1  |a research-article  |2 jats 
949 |B NATIONALLICENCE  |F NATIONALLICENCE  |b NL-springer 
950 |B NATIONALLICENCE  |P 856  |E 40  |u https://doi.org/10.1007/s00397-014-0824-9  |q text/html  |z Onlinezugriff via DOI 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Bharadwaj  |D N.  |u Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, 61801, Urbana, IL, USA  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Ewoldt  |D Randy  |u Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, 61801, Urbana, IL, USA  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Rheologica Acta  |d Springer Berlin Heidelberg  |g 54/3(2015-03-01), 223-233  |x 0035-4511  |q 54:3<223  |1 2015  |2 54  |o 397